A General Palladium-Catalyzed Coupling of Aryl Bromides/Triflates and Thiols

A General Palladium-Catalyzed Coupling of Aryl Bromides/Triflates and Thiols

We have developed an efficient palladium-catalyzed carbon−sulfur bond formation reaction of aryl bromides, triflates, and activated aryl chloride. Using this protocol, we have shown tolerance to a wide variety of aryl thiols and alkyl thiols that can also be used as sulfide equivalents.

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Veröffentlicht in:Organic letters 2004-11, Vol.6 (24), p.4587-4590
Hauptverfasser: Itoh, Takahiro, Mase, Toshiaki
Format: Artikel
Sprache:eng
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Zusammenfassung:We have developed an efficient palladium-catalyzed carbon−sulfur bond formation reaction of aryl bromides, triflates, and activated aryl chloride. Using this protocol, we have shown tolerance to a wide variety of aryl thiols and alkyl thiols that can also be used as sulfide equivalents.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol047996t