Ring Closing Enyne Metathesis:  Control over Mode Selectivity and Stereoselectivity

Ring closing enyne metathesis to form 10−15-membered rings was achieved by using a tartrate-derived linker to attach ene and yne subunits. The exo/endo selectivity of the ring closure reaction of these substrates was found to be a function of ring size, whereby larger rings (12−15) give endo-product...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2004-11, Vol.126 (46), p.15074-15080
Hauptverfasser:	Hansen, Eric C, Lee, Daesung
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes - chemistry Chemical reactivity Chemistry Cyclization Exact sciences and technology Organic chemistry Reactivity and mechanisms Stereoisomerism Structure-Activity Relationship
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!