The Mechanism of Aluminum-Catalyzed Meerwein−Schmidt−Ponndorf−Verley Reduction of Carbonyls to Alcohols

The mechanistic details of the Meerwein−Schmidt−Ponndorf−Verley (MSPV) reduction of ketones to the corresponding alcohols were investigated both experimentally and computationally. Density functional theory (DFT) was used to assess the energetics of several proposed pathways (direct hydrogen transfe...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-11, Vol.126 (45), p.14796-14803
Hauptverfasser:	Cohen, Revital, Graves, Christopher R, Nguyen, SonBinh T, Martin, Jan M. L, Ratner, Mark A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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