First transition-metal complexes of S=P(NHBu t)3

First transition-metal complexes of S=P(NHBu t)3

The first transition-metal (Rh(I), Mo(VI), Ni(II)) complexes of S[double bond, length as m-dash]P(NHBu(t))(3) have been synthesized via metathetical reactions of mono-lithiated and [Rh(CO)(2)Cl](2), (Bu(t)N)(2)MoCl(2)(dme) and NiBr(2)(dme). Surprisingly in the molecular structure of the Ni(II)-compl...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2004-11 (22), p.3808-3809
Hauptverfasser: Rufanov, Konstantin A, Ziemer, Burkhard, Meisel, Manfred
Format: Artikel
Sprache:eng
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Zusammenfassung:The first transition-metal (Rh(I), Mo(VI), Ni(II)) complexes of S[double bond, length as m-dash]P(NHBu(t))(3) have been synthesized via metathetical reactions of mono-lithiated and [Rh(CO)(2)Cl](2), (Bu(t)N)(2)MoCl(2)(dme) and NiBr(2)(dme). Surprisingly in the molecular structure of the Ni(II)-complex both hard-soft (N,S) and hard-hard (N,N[prime or minute]) chelation modes of are realized.
ISSN:1477-9226
1477-9234
DOI:10.1039/b413555e