Proximity effects in self-organized binary particle-block copolymer blends
Dependent on the surface chemistry of gold nanocrystals of equal metal core size, two morphological types of self-organized block copolymer-particle blends are observed: (1) the segregation of the nanocrystals to the interfacial areas or (2) the preferential uniform distribution within one of the re...
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| Veröffentlicht in: | Physical review letters 2004-10, Vol.93 (16), p.166106.1-166106.4, Article 166106 |
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| container_end_page | 166106.4 |
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| container_issue | 16 |
| container_start_page | 166106.1 |
| container_title | Physical review letters |
| container_volume | 93 |
| creator | BOCKSTALLER, Michael R THOMAS, Edwin L |
| description | Dependent on the surface chemistry of gold nanocrystals of equal metal core size, two morphological types of self-organized block copolymer-particle blends are observed: (1) the segregation of the nanocrystals to the interfacial areas or (2) the preferential uniform distribution within one of the respective polymer domains. The confinement of the nanocrystals to the narrow interfacial regions of the microstructure in type one blends results in high local particle filling fractions and gives rise to electromagnetic coupling upon light irradiation, accompanied by a pronounced increase in absorbance. |
| doi_str_mv | 10.1103/physrevlett.93.166106 |
| format | Article |
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| source | American Physical Society Journals |
| subjects | Applied sciences Composites Exact sciences and technology Forms of application and semi-finished materials Polymer industry, paints, wood Technology of polymers |
| title | Proximity effects in self-organized binary particle-block copolymer blends |
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