Photochemical Preparation of Highly Functionalized 1-Indanones

A series of o-alkylphenyl alkyl ketones 1 were synthesized by different methods. The presence of a leaving group X adjacent to the carbonyl group is the special peculiarity of these ketones. Upon irradiation the keto carbonyl group of these compounds undergoes an n−π* excitation followed by a 1,5-hy...

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Veröffentlicht in:	Journal of organic chemistry 2004-10, Vol.69 (22), p.7582-7591
Hauptverfasser:	Wessig, Pablo, Glombitza, Clemens, Müller, Gunnar, Teubner, Janek
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology General and physical chemistry Kinetics and mechanisms Organic chemistry Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Preparations and properties Reactivity and mechanisms
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