Bound state spectroscopy of NH-He
The NH-He van der Waals complex was characterized via laser excitation of bands associated with the NH A (3)Pi-X (3)Sigma(-) transition. It was demonstrated that the ground state supports a bound level with a rotational constant of B"=0.334(2) cm(-1). These results are in agreement with the pre...
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| Veröffentlicht in: | The Journal of chemical physics 2004-10, Vol.121 (16), p.7549-7552 |
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| container_issue | 16 |
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| container_title | The Journal of chemical physics |
| container_volume | 121 |
| creator | Kerenskaya, Galina Schnupf, Udo Heaven, Michael C van der Avoird, Ad |
| description | The NH-He van der Waals complex was characterized via laser excitation of bands associated with the NH A (3)Pi-X (3)Sigma(-) transition. It was demonstrated that the ground state supports a bound level with a rotational constant of B"=0.334(2) cm(-1). These results are in agreement with the predictions of recent high-level theoretical calculations. Spin-orbit predissociation of the excited complex was observed, and the spectra yield insights regarding the NH(A)+He potential energy surfaces. |
| doi_str_mv | 10.1063/1.1808416 |
| format | Article |
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| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 2004-10, Vol.121 (16), p.7549-7552 |
| issn | 0021-9606 1089-7690 |
| language | eng |
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| source | AIP Journals Complete; AIP Digital Archive |
| title | Bound state spectroscopy of NH-He |
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