Toward Mimicking Viral Geometry with Metal-Organic Systems
Icosahedral and cuboctahedral arrangements of calixarenes, a nanometer-scale, spheroidal assembly of 12 calixarene molecules, can be manipulated in a highly controlled fashion. Previously, such assemblies were observed to favor placement of the calixarenes at the vertexes of an icosahedron. A supram...
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| Veröffentlicht in: | Journal of the American Chemical Society 2004-10, Vol.126 (41), p.13170-13171 |
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| container_end_page | 13171 |
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| container_issue | 41 |
| container_start_page | 13170 |
| container_title | Journal of the American Chemical Society |
| container_volume | 126 |
| creator | Atwood, Jerry L Barbour, Leonard J Dalgarno, Scott J Hardie, Michaele J Raston, Colin L Webb, Helen R |
| description | Icosahedral and cuboctahedral arrangements of calixarenes, a nanometer-scale, spheroidal assembly of 12 calixarene molecules, can be manipulated in a highly controlled fashion. Previously, such assemblies were observed to favor placement of the calixarenes at the vertexes of an icosahedron. A supramolecular constraint is employed in order to enforce molecular alignment and produce a cuboctahedral arrangement. The internal volume of the cuboctahedron is approximately 30% greater than that of the icosahedron. Furthermore, in stark contrast to that of the icosahedral Platonic solid, the shell of the cuboctahedral Archimedean solid is porous. |
| doi_str_mv | 10.1021/ja048058r |
| format | Article |
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| subjects | Atomic and molecular clusters Atomic and molecular physics Biomimetic Materials - chemistry Calixarenes - chemistry Exact sciences and technology Hydrophobic and Hydrophilic Interactions Lanthanoid Series Elements - chemistry Macromolecular Substances - chemistry Models, Molecular Organometallic Compounds - chemistry Phenols - chemistry Physics Spectroscopy and geometrical structure of clusters Studies of special atoms, molecules and their ions clusters Sulfonic Acids - chemistry Viruses - chemistry |
| title | Toward Mimicking Viral Geometry with Metal-Organic Systems |
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