Frustrated β-Chloride Elimination. Selective Arene Alkylation by α-Chloronorbornene Catalyzed by Electrophilic Metallocenium Ion Pairs

Single-site polymerization catalysts generated in situ via activation of Cp*MMe3 (Cp* = C5Me5; M = Ti, Zr), (CGC)MMe2 (CGC = C5Me4SiMe2NBu t ; M = Ti, Zr), and Cp2ZrMe2 with Ph3C+B(C6F5)4 - catalyze alkylation of aromatic molecules (benzene, toluene) with α-chloronorbornene at room temperature, to r...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-10, Vol.126 (39), p.12528-12540
Hauptverfasser:	Dash, Aswini K, Jensen, Tryg R, Stern, Charlotte L, Marks, Tobin J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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