Hydrogen Bonding on the Surface of Poly(2-methoxyethyl acrylate)

Hydrogen Bonding on the Surface of Poly(2-methoxyethyl acrylate)

Hydrogen bonding on the interface and in the bulk of a poly(2-methoxyethyl acrylate) (PMEA) thin film has been investigated by sum frequency generation, infrared reflection absorption, and Raman scattering measurements in different kinds of solutions containing hydrogen-bonding donators. These resul...

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Veröffentlicht in:Journal of the American Chemical Society 2004-10, Vol.126 (39), p.12198-12199
Hauptverfasser: Li, Guifeng, Ye, Shen, Morita, Shigeaki, Nishida, Takuma, Osawa, Masatoshi
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Sprache:eng
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Surface properties
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container_end_page 12199
container_issue 39
container_start_page 12198
container_title Journal of the American Chemical Society
container_volume 126
creator Li, Guifeng
Ye, Shen
Morita, Shigeaki
Nishida, Takuma
Osawa, Masatoshi
description Hydrogen bonding on the interface and in the bulk of a poly(2-methoxyethyl acrylate) (PMEA) thin film has been investigated by sum frequency generation, infrared reflection absorption, and Raman scattering measurements in different kinds of solutions containing hydrogen-bonding donators. These results indicate that the majority of the carbonyl groups on the PMEA surface are hydrogen-bonded with water or ethanol molecules, while the PMEA bulk is still dominated by the free carbonyl group.
doi_str_mv 10.1021/ja046183x
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Surface properties
title Hydrogen Bonding on the Surface of Poly(2-methoxyethyl acrylate)
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