Intermolecular Nonreductive Alkylation of Enamides via Radical−Polar Crossover

A carbon−carbon bond construction method is disclosed which involves radical addition of α-haloesters or iodoacetonitrile to enamides. Despite the presence of tri-n-butylstannane, nonreductive addition was predominant; H-atom transfer from tin hydride was not observed. Rapid iodine atom transfer to...

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Veröffentlicht in:	Organic letters 2009-02, Vol.11 (4), p.819-822
Hauptverfasser:	Friestad, Gregory K, Wu, Yaoping
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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