Metal Cation−Methyl Interactions in CB11Me12 - Salts of Me3Ge+, Me3Sn+, and Me3Pb

Oxidation of Me6M2 (M = Ge, Sn) and Me4Pb with the CB11Me12 • radical in alkane solvents produced the insoluble salts Me3M+CB11Me12 -, characterized by CP-MAS NMR and EXAFS. The cations interact with methyl groups of CB11Me12 - with coordination strength increasing from Pb to Ge. Density functional...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-09, Vol.126 (38), p.12033-12046
Hauptverfasser:	Zharov, Ilya, Weng, Tsu-Chien, Orendt, Anita M, Barich, Dewey H, Penner-Hahn, James, Grant, David M, Havlas, Zdenek, Michl, Josef
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular clusters Atomic and molecular physics Boron Compounds - chemical synthesis Boron Compounds - chemistry Cations - chemistry Exact sciences and technology Fourier Analysis Germanium - chemistry Magnetic Resonance Spectroscopy - methods Models, Molecular Physics Spectroscopy and geometrical structure of clusters Spectrum Analysis - methods Static Electricity Studies of special atoms, molecules and their ions clusters Tetraethyl Lead - analogs & derivatives Tetraethyl Lead - chemical synthesis Tetraethyl Lead - chemistry Trimethyltin Compounds - chemical synthesis Trimethyltin Compounds - chemistry
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