Effect of Additives on Chemoselectivity and Diastereoselectivity in the Catalytic Epoxidation of Chiral Allylic Alcohols with Hydrogen Peroxide and Binuclear Manganese Complexes

The catalytic oxidations of chiral allylic alcohols 2 by manganese complexes of the cyclic triamine 1,4,7-trimethyl-1,4,7-triazacyclononane (tmtacn) 1 and hydrogen peroxide as oxygen donor in the presence of co-catalyst are investigated to understand the factors that affect the catalyst selectivity....

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Veröffentlicht in:	Journal of organic chemistry 2009-02, Vol.74 (3), p.1135-1140
Hauptverfasser:	Kilic, Hamdullah, Adam, Waldemar, Alsters, Paul L
Format:	Artikel
Sprache:	eng
Schlagworte:	Aza Compounds - chemistry Catalysis Catalysts: preparations and properties Chemistry Epoxy Compounds - chemical synthesis Epoxy Compounds - chemistry Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Hydrogen Peroxide - chemistry Kinetics and mechanisms Manganese - chemistry Organic chemistry Organometallic Compounds - chemistry Oxidation-Reduction Preparations and properties Propanols - chemistry Reactivity and mechanisms Stereoisomerism Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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