Mechanistic characterization of aerobic alcohol oxidation catalyzed by Pd(OAc)(2)/pyridine including identification of the catalyst resting state and the origin of nonlinear [catalyst] dependence

The Pd(OAc)(2)/pyridine catalyst system is one of the most convenient and versatile catalyst systems for selective aerobic oxidation of organic substrates. This report describes the catalytic mechanism of Pd(OAc)(2)/pyridine-mediated oxidation of benzyl alcohol, which has been studied by gas-uptake...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-09, Vol.126 (36), p.11268-11278
Hauptverfasser:	Steinhoff, Bradley A, Guzei, Ilia A, Stahl, Shannon S
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates - chemistry Alcohols - chemistry Aldehydes - chemical synthesis Benzaldehydes - chemical synthesis Catalysis Kinetics Oxidation-Reduction Oxygen - chemistry Palladium - chemistry Pyridines - chemistry
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