An Approach to Thermodynamically Controlled Supramolecular Assembly Possessing an Integral Locking Mechanism

An Approach to Thermodynamically Controlled Supramolecular Assembly Possessing an Integral Locking Mechanism

A general approach for thermodynamically controlled molecular assembly employing carbonyl addition chemistry is exemplified with a prototypical rotaxane synthesis. Recognition−driven assembly of the rotaxane proceeds under conditions of mild base catalysis, while subsequent treatment with catalytic...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2009-01, Vol.131 (3), p.902-903
Hauptverfasser: Cagulada, Amy M, Hamilton, Darren G
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 903
container_issue 3
container_start_page 902
container_title Journal of the American Chemical Society
container_volume 131
creator Cagulada, Amy M
Hamilton, Darren G
description A general approach for thermodynamically controlled molecular assembly employing carbonyl addition chemistry is exemplified with a prototypical rotaxane synthesis. Recognition−driven assembly of the rotaxane proceeds under conditions of mild base catalysis, while subsequent treatment with catalytic acid triggers a dehydrative locking mechanism and fixes the evolved molecular architecture in place.
doi_str_mv 10.1021/ja808162b
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_66839696</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>66839696</sourcerecordid><originalsourceid>FETCH-LOGICAL-a379t-2604b0c28f0be9827cb2a723817f6a0140fae4f1621cd62eb1f06891159fe293</originalsourceid><addsrcrecordid>eNptkM9LwzAYhoMobk4P_gOSi4KHar60S9PjGP4YTBTcvXzN0q0zTWbSHvbfm7GhF0_fDx5eeF5CroE9AOPwuEHJJAhenZAhjDlLxsDFKRkyxniSS5EOyEUIm3hmXMI5GUAB4wxyGBIzsXSy3XqHak07Rxdr7Vu33FlsG4XG7OjU2c47Y_SSfvZbj60zWvUGPZ2EoNsqIh8ubiE0dkXR0pnt9MqjoXOnvva_N63WaJvQXpKzGk3QV8c5Iovnp8X0NZm_v8ymk3mCaV50CRcsq5jismaVLiTPVcUx56mEvBbIIGM16qyOwqCWgusKaiZkATAuas2LdETuDrFR67vXoSvbJihtDFrt-lAKIdNCFCKC9wdQ-WjgdV1ufdOi35XAyn2z5W-zkb05hvZVq5d_5LHKCNweAFSh3Lje26j4T9APbOSAgw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>66839696</pqid></control><display><type>article</type><title>An Approach to Thermodynamically Controlled Supramolecular Assembly Possessing an Integral Locking Mechanism</title><source>ACS Publications</source><creator>Cagulada, Amy M ; Hamilton, Darren G</creator><creatorcontrib>Cagulada, Amy M ; Hamilton, Darren G</creatorcontrib><description>A general approach for thermodynamically controlled molecular assembly employing carbonyl addition chemistry is exemplified with a prototypical rotaxane synthesis. Recognition−driven assembly of the rotaxane proceeds under conditions of mild base catalysis, while subsequent treatment with catalytic acid triggers a dehydrative locking mechanism and fixes the evolved molecular architecture in place.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja808162b</identifier><identifier>PMID: 19154171</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Journal of the American Chemical Society, 2009-01, Vol.131 (3), p.902-903</ispartof><rights>Copyright © 2009 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a379t-2604b0c28f0be9827cb2a723817f6a0140fae4f1621cd62eb1f06891159fe293</citedby><cites>FETCH-LOGICAL-a379t-2604b0c28f0be9827cb2a723817f6a0140fae4f1621cd62eb1f06891159fe293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja808162b$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja808162b$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19154171$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cagulada, Amy M</creatorcontrib><creatorcontrib>Hamilton, Darren G</creatorcontrib><title>An Approach to Thermodynamically Controlled Supramolecular Assembly Possessing an Integral Locking Mechanism</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>A general approach for thermodynamically controlled molecular assembly employing carbonyl addition chemistry is exemplified with a prototypical rotaxane synthesis. Recognition−driven assembly of the rotaxane proceeds under conditions of mild base catalysis, while subsequent treatment with catalytic acid triggers a dehydrative locking mechanism and fixes the evolved molecular architecture in place.</description><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNptkM9LwzAYhoMobk4P_gOSi4KHar60S9PjGP4YTBTcvXzN0q0zTWbSHvbfm7GhF0_fDx5eeF5CroE9AOPwuEHJJAhenZAhjDlLxsDFKRkyxniSS5EOyEUIm3hmXMI5GUAB4wxyGBIzsXSy3XqHak07Rxdr7Vu33FlsG4XG7OjU2c47Y_SSfvZbj60zWvUGPZ2EoNsqIh8ubiE0dkXR0pnt9MqjoXOnvva_N63WaJvQXpKzGk3QV8c5Iovnp8X0NZm_v8ymk3mCaV50CRcsq5jismaVLiTPVcUx56mEvBbIIGM16qyOwqCWgusKaiZkATAuas2LdETuDrFR67vXoSvbJihtDFrt-lAKIdNCFCKC9wdQ-WjgdV1ufdOi35XAyn2z5W-zkb05hvZVq5d_5LHKCNweAFSh3Lje26j4T9APbOSAgw</recordid><startdate>20090128</startdate><enddate>20090128</enddate><creator>Cagulada, Amy M</creator><creator>Hamilton, Darren G</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20090128</creationdate><title>An Approach to Thermodynamically Controlled Supramolecular Assembly Possessing an Integral Locking Mechanism</title><author>Cagulada, Amy M ; Hamilton, Darren G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a379t-2604b0c28f0be9827cb2a723817f6a0140fae4f1621cd62eb1f06891159fe293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cagulada, Amy M</creatorcontrib><creatorcontrib>Hamilton, Darren G</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cagulada, Amy M</au><au>Hamilton, Darren G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Approach to Thermodynamically Controlled Supramolecular Assembly Possessing an Integral Locking Mechanism</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2009-01-28</date><risdate>2009</risdate><volume>131</volume><issue>3</issue><spage>902</spage><epage>903</epage><pages>902-903</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>A general approach for thermodynamically controlled molecular assembly employing carbonyl addition chemistry is exemplified with a prototypical rotaxane synthesis. Recognition−driven assembly of the rotaxane proceeds under conditions of mild base catalysis, while subsequent treatment with catalytic acid triggers a dehydrative locking mechanism and fixes the evolved molecular architecture in place.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>19154171</pmid><doi>10.1021/ja808162b</doi><tpages>2</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0002-7863
ispartof Journal of the American Chemical Society, 2009-01, Vol.131 (3), p.902-903
issn 0002-7863
1520-5126
language eng
recordid cdi_proquest_miscellaneous_66839696
source ACS Publications
title An Approach to Thermodynamically Controlled Supramolecular Assembly Possessing an Integral Locking Mechanism
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T12%3A01%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20Approach%20to%20Thermodynamically%20Controlled%20Supramolecular%20Assembly%20Possessing%20an%20Integral%20Locking%20Mechanism&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Cagulada,%20Amy%20M&rft.date=2009-01-28&rft.volume=131&rft.issue=3&rft.spage=902&rft.epage=903&rft.pages=902-903&rft.issn=0002-7863&rft.eissn=1520-5126&rft_id=info:doi/10.1021/ja808162b&rft_dat=%3Cproquest_cross%3E66839696%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=66839696&rft_id=info:pmid/19154171&rfr_iscdi=true