Supported Chiral Mo-Based Complexes as Efficient Catalysts for Enantioselective Olefin Metathesis

Syntheses and catalytic activities of seven new polymer-supported chiral Mo-based complexes are disclosed. Four of the complexes are polystyrene-based, and three involve polynorbornene supports. Studies concerning the ability of the polymer-bound chiral complexes to promote an assortment of asymmetr...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-09, Vol.126 (35), p.10945-10953
Hauptverfasser:	Dolman, Sarah J, Hultzsch, Kai C, Pezet, Frédéric, Teng, Xin, Hoveyda, Amir H, Schrock, Richard R
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemical synthesis Alkenes - chemistry Catalysis Chemical reactivity Chemistry Cyclization Exact sciences and technology Molybdenum - chemistry Organic chemistry Organometallic Compounds - chemistry Plastics - chemistry Polystyrenes - chemistry Reactivity and mechanisms Stereoisomerism
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