Rhodium-Catalyzed Direct Oxidative Carbonylation of Aromatic C−H Bond with CO and Alcohols

A general protocol for the rhodium-catalyzed oxidative carbonylation of arenes to form esters has been developed. A broad substrate scope has been demonstrated allowing carbonylation of electron-rich, electron-poor, and heterocyclic arenes, and the reaction shows wide functional group tolerance and...

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Veröffentlicht in:	Journal of the American Chemical Society 2009-01, Vol.131 (2), p.729-733
Hauptverfasser:	Guan, Zheng-Hui, Ren, Zhi-Hui, Spinella, Stephen M, Yu, Shichao, Liang, Yong-Min, Zhang, Xumu
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols - chemistry Benzene Derivatives - chemistry Benzoates - chemical synthesis Benzoates - chemistry Carbon Monoxide - chemistry Catalysis Esters - chemical synthesis Oxidation-Reduction Rhodium - chemistry Sulfuric Acids - chemistry
Online-Zugang:	Volltext
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