Sign change of the Soret coefficient of poly(ethylene oxide) in water/ethanol mixtures observed by thermal diffusion forced Rayleigh scattering

Soret coefficients of the ternary system of poly(ethylene oxide) in mixed water/ethanol solvent were measured over a wide solvent composition range by means of thermal diffusion forced Rayleigh scattering. The Soret coefficient S(T) of the polymer was found to change sign as the water content of the...

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Veröffentlicht in:The Journal of chemical physics 2004-08, Vol.121 (8), p.3874-3885
Hauptverfasser: Kita, Rio, Wiegand, Simone, Luettmer-Strathmann, Jutta
Format: Artikel
Sprache:eng
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