Electronic Structures of Five-Coordinate Iron(III) Porphyrin Complexes with Highly Ruffled Porphyrin Ring

The spin states of the iron(III) complexes with a highly ruffled porphyrin ring, [Fe(TEtPrP)X] where X = F-, Cl-, Br-, I-, and ClO4 -, have been examined by 1H NMR, 13C NMR, EPR, and Mössbauer spectroscopy. While the F-, Cl-, and Br- complexes adopt a high-spin (S = 5/2) state, the I- complex exhibi...

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Veröffentlicht in:	Inorganic chemistry 2004-08, Vol.43 (16), p.5034-5043
Hauptverfasser:	Sakai, Takanori, Ohgo, Yoshiki, Hoshino, Akito, Ikeue, Takahisa, Saitoh, Takashi, Takahashi, Masashi, Nakamura, Mikio
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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