H-Point Standard Addition Method for the Selective Simultaneous Determination of Nickel and Copper Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Media
The H-point standard addition method (HPSAM) has been applied for the simultaneous determination of nickel and copper in trace levels, using 1-(2-pyridylazo)-2-naphthol (PAN) as a chromogenic reagent in aqueous Tween 80 micellar media. Under the optimum condition, the simultaneous determinations of...
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Veröffentlicht in: | Analytical Sciences 2004, Vol.20(7), pp.1095-1098 |
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description | The H-point standard addition method (HPSAM) has been applied for the simultaneous determination of nickel and copper in trace levels, using 1-(2-pyridylazo)-2-naphthol (PAN) as a chromogenic reagent in aqueous Tween 80 micellar media. Under the optimum condition, the simultaneous determinations of nickel and copper by HPSAM were performed. The absorbances at one pair of wavelengths, 548 and 579 nm, were monitored with the addition of standard solutions of copper. The method is able to accurately determine copper-to-nickel ratios of 15:1 to 1:10 (Wt/Wt). The effects of diverse ions on the determination of nickel and copper to investigate the selectivity of the method were also studied. The recommended procedure was successfully applied to some water and alloy samples. |
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Under the optimum condition, the simultaneous determinations of nickel and copper by HPSAM were performed. The absorbances at one pair of wavelengths, 548 and 579 nm, were monitored with the addition of standard solutions of copper. The method is able to accurately determine copper-to-nickel ratios of 15:1 to 1:10 (Wt/Wt). The effects of diverse ions on the determination of nickel and copper to investigate the selectivity of the method were also studied. 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Under the optimum condition, the simultaneous determinations of nickel and copper by HPSAM were performed. The absorbances at one pair of wavelengths, 548 and 579 nm, were monitored with the addition of standard solutions of copper. The method is able to accurately determine copper-to-nickel ratios of 15:1 to 1:10 (Wt/Wt). The effects of diverse ions on the determination of nickel and copper to investigate the selectivity of the method were also studied. The recommended procedure was successfully applied to some water and alloy samples.</description><subject>Alloys</subject><subject>Chemistry - methods</subject><subject>Copper - analysis</subject><subject>Hydrogen-Ion Concentration</subject><subject>Ions</subject><subject>Micelles</subject><subject>Naphthols - chemistry</subject><subject>Nickel - analysis</subject><subject>Polysorbates - analysis</subject><subject>Spectrophotometry - methods</subject><subject>Ultraviolet Rays</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpdkU1v1DAQhiMEotvCmRuyhITKIVuPP5NjtQWK1EKltufI60y6XpI4dRzQ8mf4q3g_VBAXj6V55p159WbZG6BzBqDOTG_a0bo5o3OgpXyWzYCLImdMqOfZjJZAc8UFPcqOx3FNKbCCsZfZEUhWcgF0lv2-zG-86yO5jaavTajJeV276HxPrjGufE0aH0hcIbnFFm10P9LPdVObcPTTSC4wYuhcb3YzviFfnf2OLUlqZOGHAQO5H13_QCA_ZfnNJrh605pf_kPO8t4Mq7SjJa4ndz8Re1JQcu0stq0JaX_tzKvsRZMs4utDPcnuP328W1zmV98-f1mcX-VWahFz4AUmt0vQZSPLApgVErFWJV3qhnOqONQNFFSjYKVUsCy5LqQpgTcWlLL8JHu_1x2Cf5xwjFXnxt0hO5uVUlpqRWUC3_0Hrv0UtjFUIEQhhWagE3W2p2zw4xiwqYbgOhM2FdBqm1x1SK5itNomlybeHnSnZYf1X_4QVQIu9sB6jOYBnwATorMt_iuo989W96ltVyZU2PM_caCtHw</recordid><startdate>2004</startdate><enddate>2004</enddate><creator>ESKANDARI, Habibollah</creator><creator>KAMALI, Yousef</creator><general>The Japan Society for Analytical Chemistry</general><general>Japan Science and Technology Agency</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>2004</creationdate><title>H-Point Standard Addition Method for the Selective Simultaneous Determination of Nickel and Copper Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Media</title><author>ESKANDARI, Habibollah ; KAMALI, Yousef</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c574t-138e091b179f59812c45eed690b7f330631df1807e429561b93785a913fc166c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Alloys</topic><topic>Chemistry - methods</topic><topic>Copper - analysis</topic><topic>Hydrogen-Ion Concentration</topic><topic>Ions</topic><topic>Micelles</topic><topic>Naphthols - chemistry</topic><topic>Nickel - analysis</topic><topic>Polysorbates - analysis</topic><topic>Spectrophotometry - methods</topic><topic>Ultraviolet Rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ESKANDARI, Habibollah</creatorcontrib><creatorcontrib>KAMALI, Yousef</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>ESKANDARI, Habibollah</au><au>KAMALI, Yousef</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>H-Point Standard Addition Method for the Selective Simultaneous Determination of Nickel and Copper Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Media</atitle><jtitle>Analytical Sciences</jtitle><addtitle>Anal Sci</addtitle><date>2004</date><risdate>2004</risdate><volume>20</volume><issue>7</issue><spage>1095</spage><epage>1098</epage><pages>1095-1098</pages><issn>0910-6340</issn><eissn>1348-2246</eissn><abstract>The H-point standard addition method (HPSAM) has been applied for the simultaneous determination of nickel and copper in trace levels, using 1-(2-pyridylazo)-2-naphthol (PAN) as a chromogenic reagent in aqueous Tween 80 micellar media. Under the optimum condition, the simultaneous determinations of nickel and copper by HPSAM were performed. The absorbances at one pair of wavelengths, 548 and 579 nm, were monitored with the addition of standard solutions of copper. The method is able to accurately determine copper-to-nickel ratios of 15:1 to 1:10 (Wt/Wt). The effects of diverse ions on the determination of nickel and copper to investigate the selectivity of the method were also studied. The recommended procedure was successfully applied to some water and alloy samples.</abstract><cop>Japan</cop><pub>The Japan Society for Analytical Chemistry</pub><pmid>15293410</pmid><doi>10.2116/analsci.20.1095</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Alloys Chemistry - methods Copper - analysis Hydrogen-Ion Concentration Ions Micelles Naphthols - chemistry Nickel - analysis Polysorbates - analysis Spectrophotometry - methods Ultraviolet Rays |
title | H-Point Standard Addition Method for the Selective Simultaneous Determination of Nickel and Copper Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Media |
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