H-Point Standard Addition Method for the Selective Simultaneous Determination of Nickel and Copper Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Media

The H-point standard addition method (HPSAM) has been applied for the simultaneous determination of nickel and copper in trace levels, using 1-(2-pyridylazo)-2-naphthol (PAN) as a chromogenic reagent in aqueous Tween 80 micellar media. Under the optimum condition, the simultaneous determinations of...

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Veröffentlicht in:Analytical Sciences 2004, Vol.20(7), pp.1095-1098
Hauptverfasser: ESKANDARI, Habibollah, KAMALI, Yousef
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description The H-point standard addition method (HPSAM) has been applied for the simultaneous determination of nickel and copper in trace levels, using 1-(2-pyridylazo)-2-naphthol (PAN) as a chromogenic reagent in aqueous Tween 80 micellar media. Under the optimum condition, the simultaneous determinations of nickel and copper by HPSAM were performed. The absorbances at one pair of wavelengths, 548 and 579 nm, were monitored with the addition of standard solutions of copper. The method is able to accurately determine copper-to-nickel ratios of 15:1 to 1:10 (Wt/Wt). The effects of diverse ions on the determination of nickel and copper to investigate the selectivity of the method were also studied. The recommended procedure was successfully applied to some water and alloy samples.
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subjects Alloys
Chemistry - methods
Copper - analysis
Hydrogen-Ion Concentration
Ions
Micelles
Naphthols - chemistry
Nickel - analysis
Polysorbates - analysis
Spectrophotometry - methods
Ultraviolet Rays
title H-Point Standard Addition Method for the Selective Simultaneous Determination of Nickel and Copper Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Media
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