A 3D Interlocked Structure from a 2D Template: Structural Requirements for the Assembly of a Square-Planar Metal-Coordinated [2]Rotaxane

A 3D Interlocked Structure from a 2D Template: Structural Requirements for the Assembly of a Square-Planar Metal-Coordinated [2]Rotaxane

One step beyond: The synthesis of a three‐dimensional interlocked molecular architecture (a rotaxane) from a two‐dimensional square‐planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or...

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Veröffentlicht in:Angewandte Chemie International Edition 2004-07, Vol.43 (30), p.3914-3918
Hauptverfasser: Fuller, Anne-Marie, Leigh, David A., Lusby, Paul J., Oswald, Iain D. H., Parsons, Simon, Walker, D. Barney
Format: Artikel
Sprache:eng
Schlagworte:
coordination modes
palladium
rotaxanes
template synthesis
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Zusammenfassung:One step beyond: The synthesis of a three‐dimensional interlocked molecular architecture (a rotaxane) from a two‐dimensional square‐planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200353622