Quenching effect of nickel ions on fluorescent gold nanoparticles

Herein, we reported the quenching effect of Ni 2+ on bovine serum albumin protected fluorescent gold nanoparticles (BSA-GNPs). The quenching mechanism was discussed and a static quenching mechanism was proposed. The number of binding sites ( n), apparent stability constants ( K) and corresponding th...

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Veröffentlicht in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2009, Vol.71 (5), p.1795-1798
Hauptverfasser: Zheng, Hu-Zhi, Liu, Li, Zhang, Zhu-Jun, Huang, Yu-Ming, Zhou, Dong-Bo, Hao, Jian-Yu, Lu, Yi-Hui, Chen, Su-Ming
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container_end_page 1798
container_issue 5
container_start_page 1795
container_title Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
container_volume 71
creator Zheng, Hu-Zhi
Liu, Li
Zhang, Zhu-Jun
Huang, Yu-Ming
Zhou, Dong-Bo
Hao, Jian-Yu
Lu, Yi-Hui
Chen, Su-Ming
description Herein, we reported the quenching effect of Ni 2+ on bovine serum albumin protected fluorescent gold nanoparticles (BSA-GNPs). The quenching mechanism was discussed and a static quenching mechanism was proposed. The number of binding sites ( n), apparent stability constants ( K) and corresponding thermodynamic parameters of BSA-GNPs-Ni 2+ complex were measured at different temperatures. Under optimum conditions, the fluorescence intensity of BSA-GNPs is linearly proportional to nickel concentration from 6.0 × 10 −8 mol/L to 8.0 × 10 −6 mol/L with a detection limit of 1.0 × 10 −8 mol/L. The result indicated that BSA-GNP was a potential Ni 2+ probe.
doi_str_mv 10.1016/j.saa.2008.06.040
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subjects Binding Sites - drug effects
Fluorescence
Fluorescent gold nanoparticles
Gold - chemistry
Gold - metabolism
Ions - chemistry
Ions - metabolism
Ions - pharmacology
Metal Nanoparticles - chemistry
Microscopy, Electron, Transmission
Nickel - chemistry
Nickel - metabolism
Nickel - pharmacology
Nickel ions
Quench
Serum Albumin, Bovine - pharmacology
Spectrometry, Fluorescence
title Quenching effect of nickel ions on fluorescent gold nanoparticles
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