Tailor-Made Polyelectrolyte Microcapsules: From Multilayers to Smart Containers

This review addresses the fabrication and properties of novel polyelectrolyte microcapsules, with an emphasis on their mechanical and permeability properties. Ease of preparation through layer‐by‐layer self assembly, accurate control over wall thickness as well as flexibility in the choice of consti...

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Veröffentlicht in:Angewandte Chemie International Edition 2004-07, Vol.43 (29), p.3762-3783
Hauptverfasser: Peyratout, Claire S., Dähne, Lars
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creator Peyratout, Claire S.
Dähne, Lars
description This review addresses the fabrication and properties of novel polyelectrolyte microcapsules, with an emphasis on their mechanical and permeability properties. Ease of preparation through layer‐by‐layer self assembly, accurate control over wall thickness as well as flexibility in the choice of constituents make these capsules very promising for numerous applications in materials and life science. Moreover, by engineering the inner and outer interfaces, these capsules can be used as microreactors for precipitation, crystallization, and polymerization reactions, as well as enzymatic, and heterogeneous catalysis. Wrap artists: Hollow polyelectrolyte microcapsules have promising perspectives in numerous applications, such as engineering, biotechnology, and medicine. In this Review, the recent advances in this field are presented, with a focus on the permeability properties of the capsules as well as on their application as microreactors. The picture shows a library of 15 dye‐modified capsules of poly(allylamine)/poly(styrene sulfonate).
doi_str_mv 10.1002/anie.200300568
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subjects Biocompatible Materials - chemistry
Bioreactors
Capsules - chemistry
Capsules - pharmacology
drug release
Electrolytes - chemistry
materials science
Materials Testing
microencapsulation
microreactors
Microscopy, Confocal
Microscopy, Fluorescence
Microspheres
Permeability
Polymers - chemistry
self-assembly
Stress, Mechanical
title Tailor-Made Polyelectrolyte Microcapsules: From Multilayers to Smart Containers
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