A New Model Approach for the Near-Critical Point Region: 1. Construction of the Generalized van der Waals Equation of State
To date, it has been considered that all classical equations of state (EOS) have failed to describe the properties of fluids near the critical region, where the density fluctuations have a significant influence on fluid properties. In this paper, we suggest a newly constructed equation for fluid sta...
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Veröffentlicht in: | The journal of physical chemistry. B 2008-12, Vol.112 (49), p.15725-15741 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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