Magnetic behavior and Mossbauer spectra of spin-crossover pyrazolate bridged dinuclear diiron(II) complexes: X-ray structures of high-spin and low-spin [(Fe(NCBH3)(py))2(mu-bpypz)2]
The synthesis and characterization of new spin-crossover pyrazolato bridged dinuclear [(FeII(NCS)(py))2(mu-bpypz)2] and the corresponding cyanotrihydroborato-kappaN complexes are described together with the X-ray crystal analysis of the latter in both the high-spin and low-spin states as well as the...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2004-04 (7), p.982-988 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Nakano, Keisaku Suemura, Naohiko Kawata, Satoshi Fuyuhiro, Akira Yagi, Takashi Nasu, Saburo Morimoto, Syotaro Kaizaki, Sumio |
| description | The synthesis and characterization of new spin-crossover pyrazolato bridged dinuclear [(FeII(NCS)(py))2(mu-bpypz)2] and the corresponding cyanotrihydroborato-kappaN complexes are described together with the X-ray crystal analysis of the latter in both the high-spin and low-spin states as well as the variable temperature magnetic susceptibility and/or Mossbauer spectra demonstrating the spin-crossover which exhibits an one-step process, but not a two-step one characteristic of the known bpym bridged dinuclear complexes. |
| doi_str_mv | 10.1039/b314211f |
| format | Article |
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| source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Magnetic behavior and Mossbauer spectra of spin-crossover pyrazolate bridged dinuclear diiron(II) complexes: X-ray structures of high-spin and low-spin [(Fe(NCBH3)(py))2(mu-bpypz)2] |
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