Electrospinning of Polyvinylidene Difluoride with Carbon Nanotubes: Synergistic Effects of Extensional Force and Interfacial Interaction on Crystalline Structures
Polyvinylidene difluoride (PVDF) solutions containing a very low concentration of single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) of similar surface chemistry, respectively, were electrospun, and the nanofibers formed were collected using a modified rotating disk co...
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| Veröffentlicht in: | Langmuir 2008-12, Vol.24 (23), p.13621-13626 |
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| container_title | Langmuir |
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| creator | Huang, Shu Yee, Wu Aik Tjiu, Wuiwui Chauhari Liu, Ye Kotaki, Masaya Boey, Yin Chiang Freddy Ma, Jan Liu, Tianxi Lu, Xuehong |
| description | Polyvinylidene difluoride (PVDF) solutions containing a very low concentration of single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) of similar surface chemistry, respectively, were electrospun, and the nanofibers formed were collected using a modified rotating disk collector. The polymorphic behavior and crystal orientation of the nanofibers were studied using wide-angle X-ray diffraction and infrared spectroscopy, while the nanotube alignment and interfacial interactions in the nanofibers were probed by transmission electron microscopy and Raman spectroscopy. It is shown that the interfacial interaction between the SWCNTs and PVDF and the extensional force experienced by the nanofibers in the electrospinning and collection processes can work synergistically to induce highly oriented β-form crystallites extensively. In contrast, the MWCNTs could not be well aligned along the nanofiber axis, which leads to a lower degree of crystal orientation. |
| doi_str_mv | 10.1021/la8024183 |
| format | Article |
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The polymorphic behavior and crystal orientation of the nanofibers were studied using wide-angle X-ray diffraction and infrared spectroscopy, while the nanotube alignment and interfacial interactions in the nanofibers were probed by transmission electron microscopy and Raman spectroscopy. It is shown that the interfacial interaction between the SWCNTs and PVDF and the extensional force experienced by the nanofibers in the electrospinning and collection processes can work synergistically to induce highly oriented β-form crystallites extensively. In contrast, the MWCNTs could not be well aligned along the nanofiber axis, which leads to a lower degree of crystal orientation.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la8024183</identifier><identifier>PMID: 18956851</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Colloidal state and disperse state ; Crystallization ; Electric Conductivity ; Electrochemistry ; Exact sciences and technology ; General and physical chemistry ; Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites ; Nanotubes, Carbon - chemistry ; Particle Size ; Polyvinyls - chemistry ; Spectroscopy, Fourier Transform Infrared ; Surface physical chemistry ; Surface Properties ; X-Ray Diffraction</subject><ispartof>Langmuir, 2008-12, Vol.24 (23), p.13621-13626</ispartof><rights>Copyright © 2008 American Chemical Society</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a381t-1cbdfab70b354a4d66db14c82f279f9abcf4ec63c17bac140650dcdd9344f0123</citedby><cites>FETCH-LOGICAL-a381t-1cbdfab70b354a4d66db14c82f279f9abcf4ec63c17bac140650dcdd9344f0123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/la8024183$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/la8024183$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20918049$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18956851$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Huang, Shu</creatorcontrib><creatorcontrib>Yee, Wu Aik</creatorcontrib><creatorcontrib>Tjiu, Wuiwui Chauhari</creatorcontrib><creatorcontrib>Liu, Ye</creatorcontrib><creatorcontrib>Kotaki, Masaya</creatorcontrib><creatorcontrib>Boey, Yin Chiang Freddy</creatorcontrib><creatorcontrib>Ma, Jan</creatorcontrib><creatorcontrib>Liu, Tianxi</creatorcontrib><creatorcontrib>Lu, Xuehong</creatorcontrib><title>Electrospinning of Polyvinylidene Difluoride with Carbon Nanotubes: Synergistic Effects of Extensional Force and Interfacial Interaction on Crystalline Structures</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>Polyvinylidene difluoride (PVDF) solutions containing a very low concentration of single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) of similar surface chemistry, respectively, were electrospun, and the nanofibers formed were collected using a modified rotating disk collector. The polymorphic behavior and crystal orientation of the nanofibers were studied using wide-angle X-ray diffraction and infrared spectroscopy, while the nanotube alignment and interfacial interactions in the nanofibers were probed by transmission electron microscopy and Raman spectroscopy. It is shown that the interfacial interaction between the SWCNTs and PVDF and the extensional force experienced by the nanofibers in the electrospinning and collection processes can work synergistically to induce highly oriented β-form crystallites extensively. In contrast, the MWCNTs could not be well aligned along the nanofiber axis, which leads to a lower degree of crystal orientation.</description><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Crystallization</subject><subject>Electric Conductivity</subject><subject>Electrochemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites</subject><subject>Nanotubes, Carbon - chemistry</subject><subject>Particle Size</subject><subject>Polyvinyls - chemistry</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Surface physical chemistry</subject><subject>Surface Properties</subject><subject>X-Ray Diffraction</subject><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkcFu1DAQhi1ERbeFAy-AfAGph1A7cZyEW9luaaW2VNpytiaOXVy89mI70LwOT4qXXW0vSJbsGX_6Z_T_CL2l5CMlJT210JKS0bZ6gWa0LklRt2XzEs1Iw6qiYbw6REcxPhJCuop1r9AhbbuatzWdoT8Lq2QKPq6Nc8Y9YK_xnbfTL-MmawblFD432o4-5AL_Nuk7nkPovcO34HwaexU_4eXkVHgwMRmJF1pnwbjRWTwl5aLxDiy-8EEqDG7AVy6poEGa3P33Bpkyg_OZhykmsNbkqcsURpnGoOJrdKDBRvVmdx-jbxeL-_llcf31y9X87LqAqqWpoLIfNPQN6auaARs4H3rKZFvqsul0B73UTEleSdr0ICkjvCaDHIZsCdOEltUx-rDVXQf_c1QxiZWJUlkLTvkxCs55l03uMniyBWX2LQalxTqYFYRJUCI2gYh9IJl9txMd-5UansldAhl4vwMgSrA6gJMm7rmSdLQlbDO02HLZZvW0_4fwQ_Cmampxf7cUl23zmdQ354I864KM4tGPIacQ_7PgX73LshE</recordid><startdate>20081202</startdate><enddate>20081202</enddate><creator>Huang, Shu</creator><creator>Yee, Wu Aik</creator><creator>Tjiu, Wuiwui Chauhari</creator><creator>Liu, Ye</creator><creator>Kotaki, Masaya</creator><creator>Boey, Yin Chiang Freddy</creator><creator>Ma, Jan</creator><creator>Liu, Tianxi</creator><creator>Lu, Xuehong</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20081202</creationdate><title>Electrospinning of Polyvinylidene Difluoride with Carbon Nanotubes: Synergistic Effects of Extensional Force and Interfacial Interaction on Crystalline Structures</title><author>Huang, Shu ; Yee, Wu Aik ; Tjiu, Wuiwui Chauhari ; Liu, Ye ; Kotaki, Masaya ; Boey, Yin Chiang Freddy ; Ma, Jan ; Liu, Tianxi ; Lu, Xuehong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a381t-1cbdfab70b354a4d66db14c82f279f9abcf4ec63c17bac140650dcdd9344f0123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Crystallization</topic><topic>Electric Conductivity</topic><topic>Electrochemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites</topic><topic>Nanotubes, Carbon - chemistry</topic><topic>Particle Size</topic><topic>Polyvinyls - chemistry</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Surface physical chemistry</topic><topic>Surface Properties</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Shu</creatorcontrib><creatorcontrib>Yee, Wu Aik</creatorcontrib><creatorcontrib>Tjiu, Wuiwui Chauhari</creatorcontrib><creatorcontrib>Liu, Ye</creatorcontrib><creatorcontrib>Kotaki, Masaya</creatorcontrib><creatorcontrib>Boey, Yin Chiang Freddy</creatorcontrib><creatorcontrib>Ma, Jan</creatorcontrib><creatorcontrib>Liu, Tianxi</creatorcontrib><creatorcontrib>Lu, Xuehong</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Shu</au><au>Yee, Wu Aik</au><au>Tjiu, Wuiwui Chauhari</au><au>Liu, Ye</au><au>Kotaki, Masaya</au><au>Boey, Yin Chiang Freddy</au><au>Ma, Jan</au><au>Liu, Tianxi</au><au>Lu, Xuehong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrospinning of Polyvinylidene Difluoride with Carbon Nanotubes: Synergistic Effects of Extensional Force and Interfacial Interaction on Crystalline Structures</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2008-12-02</date><risdate>2008</risdate><volume>24</volume><issue>23</issue><spage>13621</spage><epage>13626</epage><pages>13621-13626</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>Polyvinylidene difluoride (PVDF) solutions containing a very low concentration of single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) of similar surface chemistry, respectively, were electrospun, and the nanofibers formed were collected using a modified rotating disk collector. The polymorphic behavior and crystal orientation of the nanofibers were studied using wide-angle X-ray diffraction and infrared spectroscopy, while the nanotube alignment and interfacial interactions in the nanofibers were probed by transmission electron microscopy and Raman spectroscopy. It is shown that the interfacial interaction between the SWCNTs and PVDF and the extensional force experienced by the nanofibers in the electrospinning and collection processes can work synergistically to induce highly oriented β-form crystallites extensively. In contrast, the MWCNTs could not be well aligned along the nanofiber axis, which leads to a lower degree of crystal orientation.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>18956851</pmid><doi>10.1021/la8024183</doi><tpages>6</tpages></addata></record> |
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| subjects | Chemistry Colloidal state and disperse state Crystallization Electric Conductivity Electrochemistry Exact sciences and technology General and physical chemistry Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites Nanotubes, Carbon - chemistry Particle Size Polyvinyls - chemistry Spectroscopy, Fourier Transform Infrared Surface physical chemistry Surface Properties X-Ray Diffraction |
| title | Electrospinning of Polyvinylidene Difluoride with Carbon Nanotubes: Synergistic Effects of Extensional Force and Interfacial Interaction on Crystalline Structures |
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