Unimolecular Reactions of CF2ClCFClCH2F and CF2ClCF2CH2Cl: Observation of ClF Interchange

The unimolecular reactions of CF2ClCFClCH2F and CF2ClCF2CH2Cl molecules formed with 87 and 91 kcal mol−1, respectively, of vibrational energy from the recombination of CF2ClCFCl with CH2F and CF2ClCF2 with CH2Cl at room temperature have been studied by the chemical activation technique. The 2,3- and...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2008-11, Vol.112 (47), p.12117-12124
Hauptverfasser: Zaluzhna, Oksana, Simmons, Jay G, Setser, D. W, Holmes, Bert E
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Sprache:eng
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