Biomimetic Cooperative Interactions of Dried Cross-Linked Poly(N-6-aminohexylacrylamide) with Binary Mixtures of Solvent Vapors
Biomimetic cooperativity of hydration effect and effect of ethanol favorable for binding of bad organic sorbates were observed for their vapor sorption by cross-linked poly(N-6-aminohexylacrylamide) (PNAHAA) in the absence of liquid phase. The vapor sorption isotherms were determined for these syste...
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| Veröffentlicht in: | Biomacromolecules 2004-07, Vol.5 (4), p.1615-1623 |
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| container_title | Biomacromolecules |
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| creator | Gorbatchuk, Valery V Mironov, Nikolay A Solomonov, Boris N Habicher, Wolf D |
| description | Biomimetic cooperativity of hydration effect and effect of ethanol favorable for binding of bad organic sorbates were observed for their vapor sorption by cross-linked poly(N-6-aminohexylacrylamide) (PNAHAA) in the absence of liquid phase. The vapor sorption isotherms were determined for these systems by the static method of gas chromatographic headspace analysis at 298 K. The hydration above 0.09−0.13 g of H2O/(g of polymer) gives a cooperative increase in the PNAHAA binding affinity for benzene, cyclohexane, dioxane, and propanols up to a level which does not change by further hydration, indicating the polymer antiplasticization. Bad sorbates (dioxane, benzene) were observed to have a biomimetic cooperative influence on the binding of ethanol by the dried PNAHAA. This cooperativity does not occur in ternary systems with good nonhydroxylic sorbate acetonitrile. |
| doi_str_mv | 10.1021/bm049743t |
| format | Article |
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The vapor sorption isotherms were determined for these systems by the static method of gas chromatographic headspace analysis at 298 K. The hydration above 0.09−0.13 g of H2O/(g of polymer) gives a cooperative increase in the PNAHAA binding affinity for benzene, cyclohexane, dioxane, and propanols up to a level which does not change by further hydration, indicating the polymer antiplasticization. Bad sorbates (dioxane, benzene) were observed to have a biomimetic cooperative influence on the binding of ethanol by the dried PNAHAA. 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The vapor sorption isotherms were determined for these systems by the static method of gas chromatographic headspace analysis at 298 K. The hydration above 0.09−0.13 g of H2O/(g of polymer) gives a cooperative increase in the PNAHAA binding affinity for benzene, cyclohexane, dioxane, and propanols up to a level which does not change by further hydration, indicating the polymer antiplasticization. Bad sorbates (dioxane, benzene) were observed to have a biomimetic cooperative influence on the binding of ethanol by the dried PNAHAA. This cooperativity does not occur in ternary systems with good nonhydroxylic sorbate acetonitrile.</description><subject>Acetonitriles - chemistry</subject><subject>Acrylamides - chemical synthesis</subject><subject>Acrylamides - chemistry</subject><subject>Adsorption</subject><subject>Benzene - chemistry</subject><subject>Biomimetics</subject><subject>Chemical Phenomena</subject><subject>Chemistry, Physical</subject><subject>Cross-Linking Reagents - chemistry</subject><subject>Desiccation</subject><subject>Dioxanes - chemistry</subject><subject>Ethanol - chemistry</subject><subject>Polymers - chemical synthesis</subject><subject>Polymers - chemistry</subject><subject>Solvents - chemistry</subject><subject>Temperature</subject><subject>Volatilization</subject><subject>Water - chemistry</subject><issn>1525-7797</issn><issn>1526-4602</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkE1P3DAQhq2qFVDKoX8A-UJVDmlnEsfeHMv2C2n7IUF7jRxnIgyJvbUdyp7612tgVTj0MjOv5tE7mpexlwhvEEp8200gGiWq9ITtYV3KQkgon97NdaFUo3bZ8xgvAaCpRL3DdvNCCLGQe-zPifWTnShZw5ferynoZK-Jn7qUR5Osd5H7gb8Plnq-DD7GYmXdVRbf_bh5_bWQhZ6s8xd0sxm1CblMtqdj_tumC35inQ4b_sXepDnQndOZH6_JJf5Tr32IL9izQY-RDrZ9n_34-OF8-blYfft0uny3KnQlMBVioQQaFAIHjYB9Y5RSiwokaew6ZaAj08gaCKqmLnstsCyRSsJOYhZQ7bNX977r4H_NFFM72WhoHLUjP8dWStmUKKsMHt-D5vbXQEO7DnbKT7QI7W3a7b-0M3u4NZ27ifoHchtvBo62gI5Gj0PQztj4iGtqkAAPnDaxvfRzcDmL_xz8C9wXk9M</recordid><startdate>20040701</startdate><enddate>20040701</enddate><creator>Gorbatchuk, Valery V</creator><creator>Mironov, Nikolay A</creator><creator>Solomonov, Boris N</creator><creator>Habicher, Wolf D</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20040701</creationdate><title>Biomimetic Cooperative Interactions of Dried Cross-Linked Poly(N-6-aminohexylacrylamide) with Binary Mixtures of Solvent Vapors</title><author>Gorbatchuk, Valery V ; Mironov, Nikolay A ; Solomonov, Boris N ; Habicher, Wolf D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a341t-48741c1441fa101d9c7778306ea1bb7c0bec9650e03952da41221e2e1b61a4103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Acetonitriles - chemistry</topic><topic>Acrylamides - chemical synthesis</topic><topic>Acrylamides - chemistry</topic><topic>Adsorption</topic><topic>Benzene - chemistry</topic><topic>Biomimetics</topic><topic>Chemical Phenomena</topic><topic>Chemistry, Physical</topic><topic>Cross-Linking Reagents - chemistry</topic><topic>Desiccation</topic><topic>Dioxanes - chemistry</topic><topic>Ethanol - chemistry</topic><topic>Polymers - chemical synthesis</topic><topic>Polymers - chemistry</topic><topic>Solvents - chemistry</topic><topic>Temperature</topic><topic>Volatilization</topic><topic>Water - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gorbatchuk, Valery V</creatorcontrib><creatorcontrib>Mironov, Nikolay A</creatorcontrib><creatorcontrib>Solomonov, Boris N</creatorcontrib><creatorcontrib>Habicher, Wolf D</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Biomacromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gorbatchuk, Valery V</au><au>Mironov, Nikolay A</au><au>Solomonov, Boris N</au><au>Habicher, Wolf D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biomimetic Cooperative Interactions of Dried Cross-Linked Poly(N-6-aminohexylacrylamide) with Binary Mixtures of Solvent Vapors</atitle><jtitle>Biomacromolecules</jtitle><addtitle>Biomacromolecules</addtitle><date>2004-07-01</date><risdate>2004</risdate><volume>5</volume><issue>4</issue><spage>1615</spage><epage>1623</epage><pages>1615-1623</pages><issn>1525-7797</issn><eissn>1526-4602</eissn><abstract>Biomimetic cooperativity of hydration effect and effect of ethanol favorable for binding of bad organic sorbates were observed for their vapor sorption by cross-linked poly(N-6-aminohexylacrylamide) (PNAHAA) in the absence of liquid phase. The vapor sorption isotherms were determined for these systems by the static method of gas chromatographic headspace analysis at 298 K. The hydration above 0.09−0.13 g of H2O/(g of polymer) gives a cooperative increase in the PNAHAA binding affinity for benzene, cyclohexane, dioxane, and propanols up to a level which does not change by further hydration, indicating the polymer antiplasticization. Bad sorbates (dioxane, benzene) were observed to have a biomimetic cooperative influence on the binding of ethanol by the dried PNAHAA. This cooperativity does not occur in ternary systems with good nonhydroxylic sorbate acetonitrile.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>15244486</pmid><doi>10.1021/bm049743t</doi><tpages>9</tpages></addata></record> |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Acetonitriles - chemistry Acrylamides - chemical synthesis Acrylamides - chemistry Adsorption Benzene - chemistry Biomimetics Chemical Phenomena Chemistry, Physical Cross-Linking Reagents - chemistry Desiccation Dioxanes - chemistry Ethanol - chemistry Polymers - chemical synthesis Polymers - chemistry Solvents - chemistry Temperature Volatilization Water - chemistry |
| title | Biomimetic Cooperative Interactions of Dried Cross-Linked Poly(N-6-aminohexylacrylamide) with Binary Mixtures of Solvent Vapors |
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