Effect of the solute molecular structure on its enantioresolution on cellulose tris(3,5-dimethylphenylcarbamate)

The effects of the molecular structures for 13 structurally similar chiral solutes on their HPLC retention and enantioresolutions on a commercially important polysaccharide-based chiral stationary phase, cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) are studied. Among these 13 solutes, only me...

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Veröffentlicht in:	Journal of chromatography. B, Analytical technologies in the biomedical and life sciences Analytical technologies in the biomedical and life sciences, 2008-11, Vol.875 (1), p.81-92
Hauptverfasser:	Kasat, Rahul B., Wee, Siao Yee, Loh, Ji Xian, Wang, Nien-Hwa Linda, Franses, Elias I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cellulose - analogs & derivatives Cellulose - chemistry Chiral discrimination Chiralcel OD Chromatography, High Pressure Liquid - instrumentation Chromatography, High Pressure Liquid - methods Ephedrine Hydrogen bonding Molecular Structure Pharmaceutical Preparations - isolation & purification Phenylcarbamates - chemistry Polysaccharide Spectrophotometry, Infrared Stereoisomerism Steric interactions π–π
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