Promotion of Sandmeyer hydroxylation (homolytic hydroxydediazoniation) and hydrodediazoniation by chelation of the copper catalyst: bidentate ligands

Relative to the rate observed for the hexa-aqua ion, Cu(OH(2))(6)(2+), chelation of the copper catalyst by certain bidentate ligands enhances the rate of hydroxydediazoniation reaction (Sandmeyer hydroxylation); the ligands also provide a source of hydrogen in competitive hydrodediazoniation (H-tran...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organic & biomolecular chemistry 2004-07, Vol.2 (13), p.1838-1855
Hauptverfasser:	Hanson, Peter, Rowell, Simon C, Walton, Paul H, Timms, Allan W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!