Indium mediated allylation of glyoxylate oxime ethers, esters and cyanoformates

Indium mediated allylation of glyoxylate oxime ethers, esters and cyanoformates

An indium mediated procedure has been developed for the allylation of activated O-functionalised oximes and nitriles as exemplified by a variety of glyoxylate derivatives. This method gives the corresponding free (or protected) amine in a one pot-process. The method is regiospecific and is carried o...

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Veröffentlicht in:Organic & biomolecular chemistry 2004-07, Vol.2 (13), p.1921-1933
Hauptverfasser: Ritson, Dougal J, Cox, Russell J, Berge, John
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container_end_page 1933
container_issue 13
container_start_page 1921
container_title Organic & biomolecular chemistry
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creator Ritson, Dougal J
Cox, Russell J
Berge, John
description An indium mediated procedure has been developed for the allylation of activated O-functionalised oximes and nitriles as exemplified by a variety of glyoxylate derivatives. This method gives the corresponding free (or protected) amine in a one pot-process. The method is regiospecific and is carried out under remarkably mild conditions so that even oxime esters can be subjected to the typical reaction conditions.
doi_str_mv 10.1039/b402764g
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source Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Indium mediated allylation of glyoxylate oxime ethers, esters and cyanoformates
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