Oxidation of tertiary benzamides by 5,10,15,20-tetraphenylporphyrinatoironIII chloride-tert-butylhydroperoxide

Tertiary benzamides are oxidized by the 5,10,15,20-tetraphenylporphyrinatoiron(III) chloride-Bu'(t)OOH system at the alpha-position of the N-alkyl groups. The major products are N-acylamides, although small amounts of secondary amides, the products of dealkylation, are also formed. Plots of ini...

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Veröffentlicht in:Organic & biomolecular chemistry 2004-07, Vol.2 (13), p.1894-1900
Hauptverfasser: Constantino, Luis, Iley, Jim
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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