Noble Gas Atoms Inside Fullerenes

Heating fullerenes at 650°C under 3000 atmospheres of the noble gases helium, neon, argon, krypton, and xenon introduces these atoms into the fullerene cages in about one in 1000 molecules. A "window" mechanism in which one or more of the carbon-carbon bonds of the cage is broken has been...

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Veröffentlicht in:	Science 1996-03, Vol.271 (5256), p.1693-1697
Hauptverfasser:	Saunders, Martin, Cross, R. James, Jiménez-Vázquez, Hugo A., Shimshi, Rinat, Khong, Anthony
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY ARGON Association, addition, insertion, cluster formation, hydrogen bonding Atomic and molecular clusters Atomic and molecular physics ATOMS Atoms & subatomic particles Carbon allotropes Chemical equilibrium CHEMICAL REACTIONS Chemistry ECOLOGICAL CONCENTRATION Energy Exact sciences and technology FULLERENES Gases Gases, Rare General and physical chemistry Heat HEATING Helium HELIUM 3 Isomers KRYPTON MOLECULAR STRUCTURE Molecules NEON Noble gases Nuclear magnetic resonance Physics RARE GASES Ring currents Scientific Concepts Spectroscopy Spectroscopy and geometrical structure of clusters Studies of special atoms, molecules and their ions clusters Theory of reactions, general kinetics Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Tritium XENON
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