Isotope effect in the hydrogen distribution in the solid solution TiN0.40H0.19D0.19
The structure of a solid solution with a combined isotope composition based on TiN 0.40 H 0.19 D 0.19 (space group ) has been studied by neutron diffraction. The isotope effect in the distribution of H and D isotopes has been found: the isotopes are located in tetrahedral interstices of the same typ...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2008-04, Vol.53 (4), p.509-514 |
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| container_title | Russian journal of inorganic chemistry |
| container_volume | 53 |
| creator | Khidirov, I. Mukhtarova, N. N. Padurets, L. N. Shilov, A. L. Zaginaichenko, S. Yu Shchur, D. V. Pishchuk, V. K. |
| description | The structure of a solid solution with a combined isotope composition based on TiN
0.40
H
0.19
D
0.19
(space group
) has been studied by neutron diffraction. The isotope effect in the distribution of H and D isotopes has been found: the isotopes are located in tetrahedral interstices of the same type but with different
z
coordinates; there is splitting of 2
d
tetrahedral interstices into two groups, the protium (H) and deuterium (D). Therefore, in the ordered “layered” structure of the TiN
0.40
H
0.19
D
0.19
solid solution, two different isotopes of the same element cannot be located at the same plane perpendicular to the threefold axis. The crystal-chemical analysis of the surroundings of H and D has been performed, and considerable differences have been revealed between the coordination polyhedra surrounding different hydrogen isotopes. It has been found that, in some metal-hydrogen systems, protium and deuterium should be treated as independent chemical components. |
| doi_str_mv | 10.1134/S0036023608040049 |
| format | Article |
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0.40
H
0.19
D
0.19
(space group
) has been studied by neutron diffraction. The isotope effect in the distribution of H and D isotopes has been found: the isotopes are located in tetrahedral interstices of the same type but with different
z
coordinates; there is splitting of 2
d
tetrahedral interstices into two groups, the protium (H) and deuterium (D). Therefore, in the ordered “layered” structure of the TiN
0.40
H
0.19
D
0.19
solid solution, two different isotopes of the same element cannot be located at the same plane perpendicular to the threefold axis. The crystal-chemical analysis of the surroundings of H and D has been performed, and considerable differences have been revealed between the coordination polyhedra surrounding different hydrogen isotopes. It has been found that, in some metal-hydrogen systems, protium and deuterium should be treated as independent chemical components.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023608040049</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Synthesis and Properties of Inorganic Compounds</subject><ispartof>Russian journal of inorganic chemistry, 2008-04, Vol.53 (4), p.509-514</ispartof><rights>MAIK Nauka 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-3fb3d83e5aa89ad89efe4342b42b63d67eb396bafe4afed0cdc2ea6664431e8b3</citedby><cites>FETCH-LOGICAL-c249t-3fb3d83e5aa89ad89efe4342b42b63d67eb396bafe4afed0cdc2ea6664431e8b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023608040049$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023608040049$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Khidirov, I.</creatorcontrib><creatorcontrib>Mukhtarova, N. N.</creatorcontrib><creatorcontrib>Padurets, L. N.</creatorcontrib><creatorcontrib>Shilov, A. L.</creatorcontrib><creatorcontrib>Zaginaichenko, S. Yu</creatorcontrib><creatorcontrib>Shchur, D. V.</creatorcontrib><creatorcontrib>Pishchuk, V. K.</creatorcontrib><title>Isotope effect in the hydrogen distribution in the solid solution TiN0.40H0.19D0.19</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The structure of a solid solution with a combined isotope composition based on TiN
0.40
H
0.19
D
0.19
(space group
) has been studied by neutron diffraction. The isotope effect in the distribution of H and D isotopes has been found: the isotopes are located in tetrahedral interstices of the same type but with different
z
coordinates; there is splitting of 2
d
tetrahedral interstices into two groups, the protium (H) and deuterium (D). Therefore, in the ordered “layered” structure of the TiN
0.40
H
0.19
D
0.19
solid solution, two different isotopes of the same element cannot be located at the same plane perpendicular to the threefold axis. The crystal-chemical analysis of the surroundings of H and D has been performed, and considerable differences have been revealed between the coordination polyhedra surrounding different hydrogen isotopes. It has been found that, in some metal-hydrogen systems, protium and deuterium should be treated as independent chemical components.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Synthesis and Properties of Inorganic Compounds</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9UE1PwzAMjRBIjMEP4NYTt458NUuPaHxs0gSHjXOUNu6WqWtGkh7270lVOCEh-dmS33uWbYTuCZ4RwvjjBmMmME2QmGPMyws0IQUjuRSEXaLJQOcDf41uQjgkBcdzOUGbVXDRnSCDpoE6ZrbL4h6y_dl4t4MuMzZEb6s-Wtf9ksG11gx57G7tO55xvEyblM9DukVXjW4D3P3UKfp8fdkulvn64221eFrnNeVlzFlTMSMZFFrLUhtZQgOccVqlEMyIOVSsFJVO3QSDa1NT0EIIzhkBWbEpehjnnrz76iFEdbShhrbVHbg-KCZoQTAlSUhGYe1dCB4adfL2qP1ZEayG96k_70seOnpC0nY78Orget-le_4xfQNh9nCS</recordid><startdate>20080401</startdate><enddate>20080401</enddate><creator>Khidirov, I.</creator><creator>Mukhtarova, N. N.</creator><creator>Padurets, L. N.</creator><creator>Shilov, A. L.</creator><creator>Zaginaichenko, S. Yu</creator><creator>Shchur, D. V.</creator><creator>Pishchuk, V. K.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20080401</creationdate><title>Isotope effect in the hydrogen distribution in the solid solution TiN0.40H0.19D0.19</title><author>Khidirov, I. ; Mukhtarova, N. N. ; Padurets, L. N. ; Shilov, A. L. ; Zaginaichenko, S. Yu ; Shchur, D. V. ; Pishchuk, V. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-3fb3d83e5aa89ad89efe4342b42b63d67eb396bafe4afed0cdc2ea6664431e8b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Synthesis and Properties of Inorganic Compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khidirov, I.</creatorcontrib><creatorcontrib>Mukhtarova, N. N.</creatorcontrib><creatorcontrib>Padurets, L. N.</creatorcontrib><creatorcontrib>Shilov, A. L.</creatorcontrib><creatorcontrib>Zaginaichenko, S. Yu</creatorcontrib><creatorcontrib>Shchur, D. V.</creatorcontrib><creatorcontrib>Pishchuk, V. K.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khidirov, I.</au><au>Mukhtarova, N. N.</au><au>Padurets, L. N.</au><au>Shilov, A. L.</au><au>Zaginaichenko, S. Yu</au><au>Shchur, D. V.</au><au>Pishchuk, V. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isotope effect in the hydrogen distribution in the solid solution TiN0.40H0.19D0.19</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2008-04-01</date><risdate>2008</risdate><volume>53</volume><issue>4</issue><spage>509</spage><epage>514</epage><pages>509-514</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The structure of a solid solution with a combined isotope composition based on TiN
0.40
H
0.19
D
0.19
(space group
) has been studied by neutron diffraction. The isotope effect in the distribution of H and D isotopes has been found: the isotopes are located in tetrahedral interstices of the same type but with different
z
coordinates; there is splitting of 2
d
tetrahedral interstices into two groups, the protium (H) and deuterium (D). Therefore, in the ordered “layered” structure of the TiN
0.40
H
0.19
D
0.19
solid solution, two different isotopes of the same element cannot be located at the same plane perpendicular to the threefold axis. The crystal-chemical analysis of the surroundings of H and D has been performed, and considerable differences have been revealed between the coordination polyhedra surrounding different hydrogen isotopes. It has been found that, in some metal-hydrogen systems, protium and deuterium should be treated as independent chemical components.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0036023608040049</doi><tpages>6</tpages></addata></record> |
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| language | eng |
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| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Synthesis and Properties of Inorganic Compounds |
| title | Isotope effect in the hydrogen distribution in the solid solution TiN0.40H0.19D0.19 |
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