Predictive control and verification of conversion kinetics and polymer molecular weight in semi-batch free radical homopolymer reactions

Polymer molar mass distributions critically affect macroscopic characteristics and performance of polymeric materials. While multi-detector methods coupled to size exclusion chromatography (SEC) are widely used to measure endproduct mass distributions, less progress has been made in simultaneously c...

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Veröffentlicht in:	European polymer journal 2009-08, Vol.45 (8), p.2288-2303
Hauptverfasser:	Kreft, Tomasz, Reed, Wayne F.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Light scattering Organic polymers Physicochemistry of polymers Polymer characterization Polymerization Polymerization kinetics Preparation, kinetics, thermodynamics, mechanism and catalysts Reaction control Reaction monitoring
Online-Zugang:	Volltext
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