Near-ultraviolet femtosecond laser ionization of dioxins in gas chromatography/time-of-flight mass spectrometry

Gas chromatography/multiphoton ionization/time-of-flight mass spectrometry (GC/MPI/TOF-MS) was applied to the trace analysis of polychlorinated dibenzo- p-dioxins and polychlorinated dibenzofurans (PCDD/Fs). To determine the optimum wavelength for analysis of PCDD/Fs, the wavelength of the femtoseco...

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Veröffentlicht in:Analytica chimica acta 2009-01, Vol.632 (2), p.229-233
Hauptverfasser: Yamaguchi, Satoshi, Kira, Fumiaki, Miyoshi, Yuki, Uchimura, Tomohiro, Watanabe-Ezoe, Yuka, Zaitsu, Shin-ichi, Imasaka, Tomoko, Imasaka, Totaro
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container_end_page 233
container_issue 2
container_start_page 229
container_title Analytica chimica acta
container_volume 632
creator Yamaguchi, Satoshi
Kira, Fumiaki
Miyoshi, Yuki
Uchimura, Tomohiro
Watanabe-Ezoe, Yuka
Zaitsu, Shin-ichi
Imasaka, Tomoko
Imasaka, Totaro
description Gas chromatography/multiphoton ionization/time-of-flight mass spectrometry (GC/MPI/TOF-MS) was applied to the trace analysis of polychlorinated dibenzo- p-dioxins and polychlorinated dibenzofurans (PCDD/Fs). To determine the optimum wavelength for analysis of PCDD/Fs, the wavelength of the femtosecond laser utilized for multiphoton ionization was converted to near-ultraviolet status using stimulated Raman scattering. A femtosecond laser emitting at 300 nm completely eliminated the background signal arising from the bleeding compounds generated from a stationary phase of the capillary column in GC.
doi_str_mv 10.1016/j.aca.2008.11.005
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derivatives</subject><subject>Polychlorinated Dibenzodioxins - analysis</subject><subject>Polychlorinated Dibenzodioxins - chemistry</subject><subject>Sensitivity and Specificity</subject><subject>Spectrometric and optical methods</subject><subject>Spectrum Analysis, Raman</subject><subject>Temperature</subject><subject>Time Factors</subject><subject>Time-of-flight mass spectrometry</subject><subject>Ultraviolet Rays</subject><issn>0003-2670</issn><issn>1873-4324</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU1v1DAQhi0EotvCD-CCfKG3pOPY-bA4oYoWpKpc4GxNnMmuV0m82N6K7a_Hq13BDU6jkZ8Zj96HsXcCSgGiudmWaLGsALpSiBKgfsFWomtloWSlXrIVAMiialq4YJcxbnNbCVCv2YXQQgDobsX8I2Eo9lMK-OT8RImPNCcfyfpl4BNGCtz5xT1jyoX7kQ_O_3JL5G7ha4zcboKfMfl1wN3mcJPcTIUfi3Fy603iM8bI445syhSlcHjDXo04RXp7rlfsx93n77dfiodv919vPz0UtgadCiVUJXXTS9FgA1JD1WI99l3btSq_YF01uu4lKZS6VXasRd0PKAGGTEndyyt2fdq7C_7nnmIys4uWpgkX8vtoZAOdalv1X1DoRlf5nAyKE2iDjzHQaHbBzRgORoA56jBbk3WYow4jhMk68sz78_J9P9Pwd-KcfwY-nAGMFqcx4GJd_MNlXa2smuPnH08c5cyeHAUTraPF0uBCDtcM3v3jjN8Ppahr</recordid><startdate>20090126</startdate><enddate>20090126</enddate><creator>Yamaguchi, Satoshi</creator><creator>Kira, Fumiaki</creator><creator>Miyoshi, Yuki</creator><creator>Uchimura, Tomohiro</creator><creator>Watanabe-Ezoe, Yuka</creator><creator>Zaitsu, Shin-ichi</creator><creator>Imasaka, Tomoko</creator><creator>Imasaka, Totaro</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U7</scope><scope>C1K</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20090126</creationdate><title>Near-ultraviolet femtosecond laser ionization of dioxins in gas chromatography/time-of-flight mass spectrometry</title><author>Yamaguchi, Satoshi ; 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subjects Air Pollutants - analysis
Air Pollutants - chemistry
Analytical chemistry
Benzofurans - analysis
Benzofurans - chemistry
Chemistry
Chromatographic methods and physical methods associated with chromatography
Dibenzofurans, Polychlorinated
Dioxins - analysis
Dioxins - chemistry
Exact sciences and technology
Femtosecond laser
Gas chromatographic methods
Gas chromatography
Gas Chromatography-Mass Spectrometry
Lasers
Multiphoton ionization
Polychlorinated dibenzo- p-dioxins and polychlorinated dibenzofurans
Polychlorinated Dibenzodioxins - analogs & derivatives
Polychlorinated Dibenzodioxins - analysis
Polychlorinated Dibenzodioxins - chemistry
Sensitivity and Specificity
Spectrometric and optical methods
Spectrum Analysis, Raman
Temperature
Time Factors
Time-of-flight mass spectrometry
Ultraviolet Rays
title Near-ultraviolet femtosecond laser ionization of dioxins in gas chromatography/time-of-flight mass spectrometry
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