Improved etching method for microelectronic devices with supercritical carbon dioxide

Aqueous etchants used in traditional wet etching for the production of integrated circuits and MEMS devices hinder the processes and pose environmental difficulties. Therefore, we developed an improved dry etching method with HF/Pyridine (7:3) in supercritical carbon dioxide. Etch rates of BPSG, P-T...

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Veröffentlicht in:Microelectronic engineering 2009-02, Vol.86 (2), p.128-131
Hauptverfasser: Bae, Jae Hyun, Alam, Md. Zahangir, Jung, Jae Mok, Gal, Yeong-Soon, Lee, Hyosan, Kim, Hyun Gyu, Lim, Kwon Taek
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container_end_page 131
container_issue 2
container_start_page 128
container_title Microelectronic engineering
container_volume 86
creator Bae, Jae Hyun
Alam, Md. Zahangir
Jung, Jae Mok
Gal, Yeong-Soon
Lee, Hyosan
Kim, Hyun Gyu
Lim, Kwon Taek
description Aqueous etchants used in traditional wet etching for the production of integrated circuits and MEMS devices hinder the processes and pose environmental difficulties. Therefore, we developed an improved dry etching method with HF/Pyridine (7:3) in supercritical carbon dioxide. Etch rates of BPSG, P-TEOS, Thermal SiO 2 and SiN with dry etching method were several times higher than those in wet etching. Etch rates were found to be a function of temperature, HF concentration, and the kind of co-solvents. The presence of alcoholic co-solvents, especially IPA with HF/Pyridine etchant greatly increased the etch rate of BPSG. Etch selectivity could be controlled with the etchant concentration.
doi_str_mv 10.1016/j.mee.2008.10.003
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subjects Applied sciences
Design. Technologies. Operation analysis. Testing
Electronics
Etching
Exact sciences and technology
Integrated circuits
MEMS
Micro- and nanoelectromechanical devices (mems/nems)
Sacrificial oxide
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
SiN
Supercritical carbon dioxide
title Improved etching method for microelectronic devices with supercritical carbon dioxide
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