Electrospun nanofiber reinforced and toughened composites through in situ nano-interface formation
PAN core–PMMA shell nanofiber fabric was prepared by electrospinning of polymer blends to reinforce 2,2-bis-[4-(methacryloxypropoxy)-phenyl]-propane (Bis-GMA) a dental resin system. The core–shell structure of the PAN–PMMA nanofiber was confirmed by scanning electron microscopy (SEM) and transmissio...
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| Veröffentlicht in: | Composites science and technology 2008-12, Vol.68 (15), p.3322-3329 |
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| container_title | Composites science and technology |
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| creator | Lin, Song Cai, Qing Ji, Jianying Sui, Gang Yu, Yunhua Yang, Xiaoping Ma, Qi Wei, Yan Deng, Xuliang |
| description | PAN core–PMMA shell nanofiber fabric was prepared by electrospinning of polymer blends to reinforce 2,2-bis-[4-(methacryloxypropoxy)-phenyl]-propane (Bis-GMA) a dental resin system. The core–shell structure of the PAN–PMMA nanofiber was confirmed by scanning electron microscopy (SEM) and transmission electron microscope/energy dispersive spectroscopy (TEM/EDS) observation. The flexural properties and dynamic mechanical properties of the PAN–PMMA nanofiber reinforced Bis-GMA composites were studied. Results showed that PMMA shell was partly dissolved with the Bis-GMA resin. After photopolymerization, liner PMMA chains interpenetrated and entangled with the dental resin network, which resulted in an in situ nano-interface in the shell structure. Improvement of the mechanical properties of the PAN–PMMA nanofiber reinforced Bis-GMA composites has been achieved through this nano-interface formation. |
| doi_str_mv | 10.1016/j.compscitech.2008.08.033 |
| format | Article |
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The core–shell structure of the PAN–PMMA nanofiber was confirmed by scanning electron microscopy (SEM) and transmission electron microscope/energy dispersive spectroscopy (TEM/EDS) observation. The flexural properties and dynamic mechanical properties of the PAN–PMMA nanofiber reinforced Bis-GMA composites were studied. Results showed that PMMA shell was partly dissolved with the Bis-GMA resin. After photopolymerization, liner PMMA chains interpenetrated and entangled with the dental resin network, which resulted in an in situ nano-interface in the shell structure. Improvement of the mechanical properties of the PAN–PMMA nanofiber reinforced Bis-GMA composites has been achieved through this nano-interface formation.</description><identifier>ISSN: 0266-3538</identifier><identifier>EISSN: 1879-1050</identifier><identifier>DOI: 10.1016/j.compscitech.2008.08.033</identifier><identifier>CODEN: CSTCEH</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>A Fiber ; A Nano-composite ; Applied sciences ; B Interface ; Biological and medical sciences ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; Medical sciences ; Polymer industry, paints, wood ; Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases ; Technology of polymers ; Technology. Biomaterials. Equipments</subject><ispartof>Composites science and technology, 2008-12, Vol.68 (15), p.3322-3329</ispartof><rights>2008 Elsevier Ltd</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c448t-89bdff263ed94be4748034672153311917393e5da48034988fba76b6480909f03</citedby><cites>FETCH-LOGICAL-c448t-89bdff263ed94be4748034672153311917393e5da48034988fba76b6480909f03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0266353808003084$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20938811$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lin, Song</creatorcontrib><creatorcontrib>Cai, Qing</creatorcontrib><creatorcontrib>Ji, Jianying</creatorcontrib><creatorcontrib>Sui, Gang</creatorcontrib><creatorcontrib>Yu, Yunhua</creatorcontrib><creatorcontrib>Yang, Xiaoping</creatorcontrib><creatorcontrib>Ma, Qi</creatorcontrib><creatorcontrib>Wei, Yan</creatorcontrib><creatorcontrib>Deng, Xuliang</creatorcontrib><title>Electrospun nanofiber reinforced and toughened composites through in situ nano-interface formation</title><title>Composites science and technology</title><description>PAN core–PMMA shell nanofiber fabric was prepared by electrospinning of polymer blends to reinforce 2,2-bis-[4-(methacryloxypropoxy)-phenyl]-propane (Bis-GMA) a dental resin system. The core–shell structure of the PAN–PMMA nanofiber was confirmed by scanning electron microscopy (SEM) and transmission electron microscope/energy dispersive spectroscopy (TEM/EDS) observation. The flexural properties and dynamic mechanical properties of the PAN–PMMA nanofiber reinforced Bis-GMA composites were studied. Results showed that PMMA shell was partly dissolved with the Bis-GMA resin. After photopolymerization, liner PMMA chains interpenetrated and entangled with the dental resin network, which resulted in an in situ nano-interface in the shell structure. Improvement of the mechanical properties of the PAN–PMMA nanofiber reinforced Bis-GMA composites has been achieved through this nano-interface formation.</description><subject>A Fiber</subject><subject>A Nano-composite</subject><subject>Applied sciences</subject><subject>B Interface</subject><subject>Biological and medical sciences</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Medical sciences</subject><subject>Polymer industry, paints, wood</subject><subject>Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases</subject><subject>Technology of polymers</subject><subject>Technology. Biomaterials. 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Transplantations, organ and tissue grafts. Graft diseases</topic><topic>Technology of polymers</topic><topic>Technology. Biomaterials. Equipments</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Song</creatorcontrib><creatorcontrib>Cai, Qing</creatorcontrib><creatorcontrib>Ji, Jianying</creatorcontrib><creatorcontrib>Sui, Gang</creatorcontrib><creatorcontrib>Yu, Yunhua</creatorcontrib><creatorcontrib>Yang, Xiaoping</creatorcontrib><creatorcontrib>Ma, Qi</creatorcontrib><creatorcontrib>Wei, Yan</creatorcontrib><creatorcontrib>Deng, Xuliang</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Composites science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Song</au><au>Cai, Qing</au><au>Ji, Jianying</au><au>Sui, Gang</au><au>Yu, Yunhua</au><au>Yang, Xiaoping</au><au>Ma, Qi</au><au>Wei, Yan</au><au>Deng, Xuliang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrospun nanofiber reinforced and toughened composites through in situ nano-interface formation</atitle><jtitle>Composites science and technology</jtitle><date>2008-12-01</date><risdate>2008</risdate><volume>68</volume><issue>15</issue><spage>3322</spage><epage>3329</epage><pages>3322-3329</pages><issn>0266-3538</issn><eissn>1879-1050</eissn><coden>CSTCEH</coden><abstract>PAN core–PMMA shell nanofiber fabric was prepared by electrospinning of polymer blends to reinforce 2,2-bis-[4-(methacryloxypropoxy)-phenyl]-propane (Bis-GMA) a dental resin system. 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| subjects | A Fiber A Nano-composite Applied sciences B Interface Biological and medical sciences Composites Exact sciences and technology Forms of application and semi-finished materials Medical sciences Polymer industry, paints, wood Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases Technology of polymers Technology. Biomaterials. Equipments |
| title | Electrospun nanofiber reinforced and toughened composites through in situ nano-interface formation |
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