Functionalization via glycerol transesterification of polymerized soybean oil
An acylglycerol-based molecule was synthesized by the thermal polymerization (bodying) of soybean oil followed by transesterification with glycerol. Transesterification with glycerol at temperatures greater than 200°C provided the desired polyol prepolymers. The extent of bodying and quantity of gly...
Gespeichert in:
| Veröffentlicht in: | Journal of applied polymer science 2009-04, Vol.112 (1), p.19-27 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 27 |
|---|---|
| container_issue | 1 |
| container_start_page | 19 |
| container_title | Journal of applied polymer science |
| container_volume | 112 |
| creator | Lubguban, Arnold A Tu, Yuan-Chan Lozada, Zuleica R Hsieh, Fu-Hung Suppes, Galen J |
| description | An acylglycerol-based molecule was synthesized by the thermal polymerization (bodying) of soybean oil followed by transesterification with glycerol. Transesterification with glycerol at temperatures greater than 200°C provided the desired polyol prepolymers. The extent of bodying and quantity of glycerol added during the transesterification provided tunability of the polyol molecular weight and functionality. The hydroxyl numbers, acidity, and viscosity of the polyols were characterized. The polyols were evaluated in elastomers and rigid foams. Extractability analyses were performed on the polyurethane elastomer wafers to evaluate crosslinking. Rigid foaming results for the processed soy-based polyol showed excellent physicochemical properties suggesting comparability with a petroleum-based polyether polyol. |
| doi_str_mv | 10.1002/app.29382 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_35902491</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>35902491</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3922-d0b0d32eaa5f172442f0050f0cf2fa640cae2544e4ca1fd7a7eb939f60ba73da3</originalsourceid><addsrcrecordid>eNp1kE9PGzEQxS1UJFLogU_AXlqph4Wxvd5dH1FU_inQSC3q0Zp4beTWibd2Amw-fR0WuPU0o_HvPT0_Qo4pnFIAdoZ9f8okb9kemVCQTVnVrP1AJvmNlq2U4oB8TOk3AKUC6gm5vdis9NqFFXq3xd1SPDosHvygTQy-WEdcJZPWJjrr9AgEW_TBD8t825quSGFYGMxn54_IvkWfzKfXeUjuL779nF6Vs--X19PzWam5ZKzsYAEdZwZRWNqwqmIWQIAFbZnFugKNhomqMpVGarsGG7OQXNoaFtjwDvkh-TL69jH83eR4aumSNt7jyoRNUlxIYJWkGfw6gjqGlKKxqo9uiXFQFNSuMJULUy-FZfbzqykmjd7mn2uX3gUsN0ZrUWfubOSenDfD_w3V-Xz-5lyOCpeLfH5XYPyj6oY3Qv26u1Q3YjZvZDtVPPMnI28xKHyIOcX9DwaUAxVtTsD5P7aZk7s</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>35902491</pqid></control><display><type>article</type><title>Functionalization via glycerol transesterification of polymerized soybean oil</title><source>Wiley Online Library All Journals</source><creator>Lubguban, Arnold A ; Tu, Yuan-Chan ; Lozada, Zuleica R ; Hsieh, Fu-Hung ; Suppes, Galen J</creator><creatorcontrib>Lubguban, Arnold A ; Tu, Yuan-Chan ; Lozada, Zuleica R ; Hsieh, Fu-Hung ; Suppes, Galen J</creatorcontrib><description>An acylglycerol-based molecule was synthesized by the thermal polymerization (bodying) of soybean oil followed by transesterification with glycerol. Transesterification with glycerol at temperatures greater than 200°C provided the desired polyol prepolymers. The extent of bodying and quantity of glycerol added during the transesterification provided tunability of the polyol molecular weight and functionality. The hydroxyl numbers, acidity, and viscosity of the polyols were characterized. The polyols were evaluated in elastomers and rigid foams. Extractability analyses were performed on the polyurethane elastomer wafers to evaluate crosslinking. Rigid foaming results for the processed soy-based polyol showed excellent physicochemical properties suggesting comparability with a petroleum-based polyether polyol.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.29382</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Cellular ; crosslinking ; elastomers ; esterification ; Exact sciences and technology ; Forms of application and semi-finished materials ; oligomers ; Polymer industry, paints, wood ; polyurethanes ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 2009-04, Vol.112 (1), p.19-27</ispartof><rights>Copyright © 2008 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3922-d0b0d32eaa5f172442f0050f0cf2fa640cae2544e4ca1fd7a7eb939f60ba73da3</citedby><cites>FETCH-LOGICAL-c3922-d0b0d32eaa5f172442f0050f0cf2fa640cae2544e4ca1fd7a7eb939f60ba73da3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.29382$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.29382$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21151656$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lubguban, Arnold A</creatorcontrib><creatorcontrib>Tu, Yuan-Chan</creatorcontrib><creatorcontrib>Lozada, Zuleica R</creatorcontrib><creatorcontrib>Hsieh, Fu-Hung</creatorcontrib><creatorcontrib>Suppes, Galen J</creatorcontrib><title>Functionalization via glycerol transesterification of polymerized soybean oil</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>An acylglycerol-based molecule was synthesized by the thermal polymerization (bodying) of soybean oil followed by transesterification with glycerol. Transesterification with glycerol at temperatures greater than 200°C provided the desired polyol prepolymers. The extent of bodying and quantity of glycerol added during the transesterification provided tunability of the polyol molecular weight and functionality. The hydroxyl numbers, acidity, and viscosity of the polyols were characterized. The polyols were evaluated in elastomers and rigid foams. Extractability analyses were performed on the polyurethane elastomer wafers to evaluate crosslinking. Rigid foaming results for the processed soy-based polyol showed excellent physicochemical properties suggesting comparability with a petroleum-based polyether polyol.</description><subject>Applied sciences</subject><subject>Cellular</subject><subject>crosslinking</subject><subject>elastomers</subject><subject>esterification</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>oligomers</subject><subject>Polymer industry, paints, wood</subject><subject>polyurethanes</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp1kE9PGzEQxS1UJFLogU_AXlqph4Wxvd5dH1FU_inQSC3q0Zp4beTWibd2Amw-fR0WuPU0o_HvPT0_Qo4pnFIAdoZ9f8okb9kemVCQTVnVrP1AJvmNlq2U4oB8TOk3AKUC6gm5vdis9NqFFXq3xd1SPDosHvygTQy-WEdcJZPWJjrr9AgEW_TBD8t825quSGFYGMxn54_IvkWfzKfXeUjuL779nF6Vs--X19PzWam5ZKzsYAEdZwZRWNqwqmIWQIAFbZnFugKNhomqMpVGarsGG7OQXNoaFtjwDvkh-TL69jH83eR4aumSNt7jyoRNUlxIYJWkGfw6gjqGlKKxqo9uiXFQFNSuMJULUy-FZfbzqykmjd7mn2uX3gUsN0ZrUWfubOSenDfD_w3V-Xz-5lyOCpeLfH5XYPyj6oY3Qv26u1Q3YjZvZDtVPPMnI28xKHyIOcX9DwaUAxVtTsD5P7aZk7s</recordid><startdate>20090405</startdate><enddate>20090405</enddate><creator>Lubguban, Arnold A</creator><creator>Tu, Yuan-Chan</creator><creator>Lozada, Zuleica R</creator><creator>Hsieh, Fu-Hung</creator><creator>Suppes, Galen J</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20090405</creationdate><title>Functionalization via glycerol transesterification of polymerized soybean oil</title><author>Lubguban, Arnold A ; Tu, Yuan-Chan ; Lozada, Zuleica R ; Hsieh, Fu-Hung ; Suppes, Galen J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3922-d0b0d32eaa5f172442f0050f0cf2fa640cae2544e4ca1fd7a7eb939f60ba73da3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Cellular</topic><topic>crosslinking</topic><topic>elastomers</topic><topic>esterification</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>oligomers</topic><topic>Polymer industry, paints, wood</topic><topic>polyurethanes</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lubguban, Arnold A</creatorcontrib><creatorcontrib>Tu, Yuan-Chan</creatorcontrib><creatorcontrib>Lozada, Zuleica R</creatorcontrib><creatorcontrib>Hsieh, Fu-Hung</creatorcontrib><creatorcontrib>Suppes, Galen J</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lubguban, Arnold A</au><au>Tu, Yuan-Chan</au><au>Lozada, Zuleica R</au><au>Hsieh, Fu-Hung</au><au>Suppes, Galen J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Functionalization via glycerol transesterification of polymerized soybean oil</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2009-04-05</date><risdate>2009</risdate><volume>112</volume><issue>1</issue><spage>19</spage><epage>27</epage><pages>19-27</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>An acylglycerol-based molecule was synthesized by the thermal polymerization (bodying) of soybean oil followed by transesterification with glycerol. Transesterification with glycerol at temperatures greater than 200°C provided the desired polyol prepolymers. The extent of bodying and quantity of glycerol added during the transesterification provided tunability of the polyol molecular weight and functionality. The hydroxyl numbers, acidity, and viscosity of the polyols were characterized. The polyols were evaluated in elastomers and rigid foams. Extractability analyses were performed on the polyurethane elastomer wafers to evaluate crosslinking. Rigid foaming results for the processed soy-based polyol showed excellent physicochemical properties suggesting comparability with a petroleum-based polyether polyol.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.29382</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8995 |
| ispartof | Journal of applied polymer science, 2009-04, Vol.112 (1), p.19-27 |
| issn | 0021-8995 1097-4628 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_35902491 |
| source | Wiley Online Library All Journals |
| subjects | Applied sciences Cellular crosslinking elastomers esterification Exact sciences and technology Forms of application and semi-finished materials oligomers Polymer industry, paints, wood polyurethanes Technology of polymers |
| title | Functionalization via glycerol transesterification of polymerized soybean oil |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T22%3A59%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Functionalization%20via%20glycerol%20transesterification%20of%20polymerized%20soybean%20oil&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Lubguban,%20Arnold%20A&rft.date=2009-04-05&rft.volume=112&rft.issue=1&rft.spage=19&rft.epage=27&rft.pages=19-27&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.29382&rft_dat=%3Cproquest_cross%3E35902491%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=35902491&rft_id=info:pmid/&rfr_iscdi=true |