Comparison of the Effects of an Ionic Liquid and Other Salts on the Properties of Electrospun Fibers, 2 - Poly(vinyl alcohol)

Understanding the effect of conductivity in electrospinning solutions is crucial in order to improve or control the electrospinning process. In this paper the effect of adding small amounts (0.039–0.259 mol · kg−1) of three different conductive additives to aqueous solutions of polyvinyl alcohol has...

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Veröffentlicht in:Macromolecular materials and engineering 2009-01, Vol.294 (1), p.45-53
Hauptverfasser: Arumugam, Ganesh Kumar, Khan, Sourabh, Heiden, Patricia A.
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Heiden, Patricia A.
description Understanding the effect of conductivity in electrospinning solutions is crucial in order to improve or control the electrospinning process. In this paper the effect of adding small amounts (0.039–0.259 mol · kg−1) of three different conductive additives to aqueous solutions of polyvinyl alcohol has been investigated. The salts were HMICl (a room temperature ionic liquid), TEBAC (a quaternary ammonium salt) and KCl. Addition of these salts caused a steady increase in the solution conductivity but the fiber diameter was typically greater than that of PVA alone, and exhibited an oscillatory trend. The oscillatory trend on the fiber diameter is attributed to fiber backbuilding and fusion that occurs prior to deposition on the collector.
doi_str_mv 10.1002/mame.200800199
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source Wiley Online Library Journals Frontfile Complete
subjects Applied sciences
electrospinning
Exact sciences and technology
ionic liquids
Machinery and processing
nanofibers
Plastics
Polymer industry, paints, wood
RTIL
Spinning
Technology of polymers
title Comparison of the Effects of an Ionic Liquid and Other Salts on the Properties of Electrospun Fibers, 2 - Poly(vinyl alcohol)
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