Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS)

The corrosion resistance of anodized Al 6061 produced by two different anodizing and sealing processes was evaluated using electrochemical impedance spectroscopy (EIS). The scanning electron microscope (SEM) was employed to determine the surface structure and the thickness of the anodized layers. Th...

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Veröffentlicht in:Corrosion science 2008-12, Vol.50 (12), p.3569-3575
Hauptverfasser: Huang, Yuelong, Shih, Hong, Huang, Huochuan, Daugherty, John, Wu, Shun, Ramanathan, Sivakami, Chang, Chris, Mansfeld, Florian
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container_end_page 3575
container_issue 12
container_start_page 3569
container_title Corrosion science
container_volume 50
creator Huang, Yuelong
Shih, Hong
Huang, Huochuan
Daugherty, John
Wu, Shun
Ramanathan, Sivakami
Chang, Chris
Mansfeld, Florian
description The corrosion resistance of anodized Al 6061 produced by two different anodizing and sealing processes was evaluated using electrochemical impedance spectroscopy (EIS). The scanning electron microscope (SEM) was employed to determine the surface structure and the thickness of the anodized layers. The EIS data revealed that there was very little change of the properties of the anodized layers for samples that were hard anodized in a mixed acid solution and sealed in hot water over a 365 day exposure period in a 3.5 wt% NaCl solution. The specific admittance A s and the breakpoint frequency f b remained constant with exposure time confirming that the hard anodizing process used in this study was very effective in providing excellent corrosion resistance of anodized Al 6061 over extended exposure periods. Some minor degradation of the protective properties of the anodized layers was observed for samples that were hard anodized in H 2SO 4 and exposed to the NaCl solution for 14 days.
doi_str_mv 10.1016/j.corsci.2008.09.008
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subjects A. Aluminum
Applied sciences
B. EIS
B. SEM
C. Oxide coatings
Corrosion
Corrosion environments
Exact sciences and technology
Metals. Metallurgy
Other surface treatments
Production techniques
Surface treatment
title Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS)
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