Copolymerization of amino acid and amino ester functionalized norbornenes via living ring-opening metathesis polymerization

Copolymerization of amino acid and amino ester functionalized norbornenes via living ring-opening metathesis polymerization

The block and random copolymerization of a series of amino acid and amino ester functionalized norbornenes by ring-opening metathesis polymerization (ROMP) induced by the well-defined molybdenum [Mo(==N-2,6-iPr---C₆H₃)(==CHCMe₂)Ph)(OCMe₃)₂] or ruthenium [Ru(PCy)₂Cl₂(==CHPh)] based initiators is desc...

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Veröffentlicht in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2008-12, Vol.46 (24), p.7985-7995
Hauptverfasser: Biagini, Stefano C.G, Gibson, Vernon C, Giles, Matthew R, Marshall, Edward L, North, Michael
Format: Artikel
Sprache:eng
Schlagworte:
amino acids
Applied sciences
biomimetic
Copolymerization
Exact sciences and technology
Organic polymers
peptides
Physicochemistry of polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
ROMP
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container_end_page 7995
container_issue 24
container_start_page 7985
container_title Journal of polymer science. Part A, Polymer chemistry
container_volume 46
creator Biagini, Stefano C.G
Gibson, Vernon C
Giles, Matthew R
Marshall, Edward L
North, Michael
description The block and random copolymerization of a series of amino acid and amino ester functionalized norbornenes by ring-opening metathesis polymerization (ROMP) induced by the well-defined molybdenum [Mo(==N-2,6-iPr---C₆H₃)(==CHCMe₂)Ph)(OCMe₃)₂] or ruthenium [Ru(PCy)₂Cl₂(==CHPh)] based initiators is described. The monomers are derived from the amino acids glycine, alanine, and isoleucine or the methyl esters of these amino acids and either endo- or exo-norborn-5-ene-2,3-dicarboxylic anhydride. Enantiomerically pure monomers afforded optically active polymers, and the mechanism and kinetics of the copolymerizations are investigated.
doi_str_mv 10.1002/pola.23098
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subjects amino acids
Applied sciences
biomimetic
Copolymerization
Exact sciences and technology
Organic polymers
peptides
Physicochemistry of polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
ROMP
title Copolymerization of amino acid and amino ester functionalized norbornenes via living ring-opening metathesis polymerization
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