Tertiary Amine — Enhanced Activity of ATRP Catalysts CuBr/TPMA and CuBr/Me6TREN

Tertiary amines were found to remarkably enhance the catalytic activity of ATRP catalysts CuBr/tris[(2‐pyridyl)methyl]amine and CuBr/tris[2‐(dimethylamino)ethylamine]. These two catalysts alone failed to polymerize MA, MMA, and styrene at reduced catalyst concentrations. With tertiary amines such as...

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Veröffentlicht in:	Macromolecular rapid communications. 2008-11, Vol.29 (22), p.1834-1838
Hauptverfasser:	Tang, Huadong, Shen, Youqing, Li, Bo‐Geng, Radosz, Maciej
Format:	Artikel
Sprache:	eng
Schlagworte:	activity enhancement amine effect Applied sciences atom transfer radical polymerization (ATRP) catalyst Exact sciences and technology kinetics (polym.) Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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