Curing kinetics of the epoxy system diglycidyl ether of bisphenol A/isophoronediamine by Fourier transform infrared spectroscopy

Curing kinetics of the epoxy system diglycidyl ether of bisphenol A/isophoronediamine by Fourier transform infrared spectroscopy

The curing reaction of an epoxy system consisting of a diglycidyl ether of bisphenol A (BADGE, n = 0) and isophoronediamine (IPD), was studied by Fourier transform infrared spectroscopy (FTIR). The degree of conversions and the reaction rates at different isothermal curing temperatures were calculat...

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Veröffentlicht in:Polymers for advanced technologies 2008-11, Vol.19 (11), p.1623-1628
Hauptverfasser: Fraga, Francisco, Vazquez, Eva C., Rodríguez-Núñez, Eugenio, Martínez-Ageitos, José Manuel
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Sprache:eng
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BADGE (n=0)
epoxy resin
FTIR
kinetic parameters
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container_end_page 1628
container_issue 11
container_start_page 1623
container_title Polymers for advanced technologies
container_volume 19
creator Fraga, Francisco
Vazquez, Eva C.
Rodríguez-Núñez, Eugenio
Martínez-Ageitos, José Manuel
description The curing reaction of an epoxy system consisting of a diglycidyl ether of bisphenol A (BADGE, n = 0) and isophoronediamine (IPD), was studied by Fourier transform infrared spectroscopy (FTIR). The degree of conversions and the reaction rates at different isothermal curing temperatures were calculated from the infrared spectra using a method derived from Beer's law. This method is based on the ratio of the height of the characteristic absorbance peak to reference absorbance peak. A kinetic model proposed by Sourour and Kamal has been used to fit experimental data. Copyright © 2008 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/pat.1178
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subjects BADGE (n=0)
epoxy resin
FTIR
kinetic parameters
title Curing kinetics of the epoxy system diglycidyl ether of bisphenol A/isophoronediamine by Fourier transform infrared spectroscopy
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