Surface functionalization with phosphazene substrates-part VII. Silicon-based materials functionalized with hexachlorocyclophosphazene
This paper investigates by means of XPS analysis the surface functionalization of soda‐lime and fused quartz glass substrates with hexachlorocyclophosphazene (HCCP), obtained by simple immersion in solutions of phosphazene in anhydrous solvents. Several experimental parameters like reaction solvent,...
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| Veröffentlicht in: | Surface and interface analysis 2009-01, Vol.41 (1), p.27-33 |
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| creator | Boscoletto, Angelo Boscolo Gleria, Mario Milani, Roberto Meda, Laura Bertani, Roberta |
| description | This paper investigates by means of XPS analysis the surface functionalization of soda‐lime and fused quartz glass substrates with hexachlorocyclophosphazene (HCCP), obtained by simple immersion in solutions of phosphazene in anhydrous solvents. Several experimental parameters like reaction solvent, temperature and treatment duration were studied, together with the influence of physisorbed water on the surface of the substrates. Phosphazene‐derived deposits resistant to tetrahydrofuran (THF) washing and vacuum drying were obtained. They presented P:N:Cl stoichiometric ratios close to 1:1:1 when the reaction and the final drying of the samples were performed at room temperature; use of higher temperatures resulted in lower nitrogen and chlorine content. The chemical nature of the films was studied by XPS peaks deconvolution which enabled us to propose a possible, temperature‐enhanced hydrolytical degradation mechanism. Copyright © 2008 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/sia.2967 |
| format | Article |
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Silicon-based materials functionalized with hexachlorocyclophosphazene</title><source>Wiley Online Library All Journals</source><creator>Boscoletto, Angelo Boscolo ; Gleria, Mario ; Milani, Roberto ; Meda, Laura ; Bertani, Roberta</creator><creatorcontrib>Boscoletto, Angelo Boscolo ; Gleria, Mario ; Milani, Roberto ; Meda, Laura ; Bertani, Roberta</creatorcontrib><description>This paper investigates by means of XPS analysis the surface functionalization of soda‐lime and fused quartz glass substrates with hexachlorocyclophosphazene (HCCP), obtained by simple immersion in solutions of phosphazene in anhydrous solvents. Several experimental parameters like reaction solvent, temperature and treatment duration were studied, together with the influence of physisorbed water on the surface of the substrates. Phosphazene‐derived deposits resistant to tetrahydrofuran (THF) washing and vacuum drying were obtained. They presented P:N:Cl stoichiometric ratios close to 1:1:1 when the reaction and the final drying of the samples were performed at room temperature; use of higher temperatures resulted in lower nitrogen and chlorine content. The chemical nature of the films was studied by XPS peaks deconvolution which enabled us to propose a possible, temperature‐enhanced hydrolytical degradation mechanism. 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Silicon-based materials functionalized with hexachlorocyclophosphazene</title><title>Surface and interface analysis</title><addtitle>Surf. Interface Anal</addtitle><description>This paper investigates by means of XPS analysis the surface functionalization of soda‐lime and fused quartz glass substrates with hexachlorocyclophosphazene (HCCP), obtained by simple immersion in solutions of phosphazene in anhydrous solvents. Several experimental parameters like reaction solvent, temperature and treatment duration were studied, together with the influence of physisorbed water on the surface of the substrates. Phosphazene‐derived deposits resistant to tetrahydrofuran (THF) washing and vacuum drying were obtained. They presented P:N:Cl stoichiometric ratios close to 1:1:1 when the reaction and the final drying of the samples were performed at room temperature; use of higher temperatures resulted in lower nitrogen and chlorine content. The chemical nature of the films was studied by XPS peaks deconvolution which enabled us to propose a possible, temperature‐enhanced hydrolytical degradation mechanism. 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Silicon-based materials functionalized with hexachlorocyclophosphazene</atitle><jtitle>Surface and interface analysis</jtitle><addtitle>Surf. Interface Anal</addtitle><date>2009-01</date><risdate>2009</risdate><volume>41</volume><issue>1</issue><spage>27</spage><epage>33</epage><pages>27-33</pages><issn>0142-2421</issn><eissn>1096-9918</eissn><coden>SIANDQ</coden><abstract>This paper investigates by means of XPS analysis the surface functionalization of soda‐lime and fused quartz glass substrates with hexachlorocyclophosphazene (HCCP), obtained by simple immersion in solutions of phosphazene in anhydrous solvents. Several experimental parameters like reaction solvent, temperature and treatment duration were studied, together with the influence of physisorbed water on the surface of the substrates. Phosphazene‐derived deposits resistant to tetrahydrofuran (THF) washing and vacuum drying were obtained. They presented P:N:Cl stoichiometric ratios close to 1:1:1 when the reaction and the final drying of the samples were performed at room temperature; use of higher temperatures resulted in lower nitrogen and chlorine content. The chemical nature of the films was studied by XPS peaks deconvolution which enabled us to propose a possible, temperature‐enhanced hydrolytical degradation mechanism. Copyright © 2008 John Wiley & Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/sia.2967</doi><tpages>7</tpages></addata></record> |
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| ispartof | Surface and interface analysis, 2009-01, Vol.41 (1), p.27-33 |
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| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Cross-disciplinary physics: materials science rheology Electron and ion emission by liquids and solids impact phenomena Exact sciences and technology Materials science phosphazenes Photoemission and photoelectron spectra Physics silica soda-lime glass surface functionalization Surface treatments XPS |
| title | Surface functionalization with phosphazene substrates-part VII. Silicon-based materials functionalized with hexachlorocyclophosphazene |
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