Some unsymmetrical nickel 1,2-dithiolene complexes as candidate materials for optics and electronics
The unsymmetrical complexes Ni(tmedt)(dddt), Ni(dpedt)(dddt), Ni(tmedt)(dmit), and Ni(dpedt)(dmio) (where tmedt is trimethylene-ethylenedithiolate, dddt is 5,6-dihydro-1,4-dithin-2,3-dithiolate, dmit is 1,3-dithiol-2-thione-4,5-dithiolate, dpedt is diphenyl-ethylenedithiolate, and dmio is 1,3-dithio...
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| Veröffentlicht in: | Solid state sciences 2008-12, Vol.10 (12), p.1729-1733 |
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| creator | Anyfantis, George C. Papavassiliou, George C. Assimomytis, Nikos Terzis, Aris Psycharis, Vassilis Raptopoulou, Catherine P. Kyritsis, Panayotis Thoma, Vladimiros Koutselas, Ioannis B. |
| description | The unsymmetrical complexes Ni(tmedt)(dddt), Ni(dpedt)(dddt), Ni(tmedt)(dmit), and Ni(dpedt)(dmio) (where tmedt is trimethylene-ethylenedithiolate, dddt is 5,6-dihydro-1,4-dithin-2,3-dithiolate, dmit is 1,3-dithiol-2-thione-4,5-dithiolate, dpedt is diphenyl-ethylenedithiolate, and dmio is 1,3-dithiol-2-one-4,5-dithiolate) were prepared and their structural and physical properties investigated. The results were compared with those obtained from similar unsymmetrical and the corresponding symmetrical complexes. The new complexes were found to be stable in air and exhibit the necessary structural and physical properties in order to be candidate materials for optical and electronic devices.
Unsymmetrical nickel 1,2-dithiolene complexes, which exhibit LUMO and HOMO levels around the Fermi energy level of Au, are suitable materials for optical and electronic devices.
[Display omitted] |
| doi_str_mv | 10.1016/j.solidstatesciences.2008.03.012 |
| format | Article |
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Unsymmetrical nickel 1,2-dithiolene complexes, which exhibit LUMO and HOMO levels around the Fermi energy level of Au, are suitable materials for optical and electronic devices.
[Display omitted]</description><identifier>ISSN: 1293-2558</identifier><identifier>EISSN: 1873-3085</identifier><identifier>DOI: 10.1016/j.solidstatesciences.2008.03.012</identifier><language>eng</language><publisher>Issy-les-Moulineaux: Elsevier Masson SAS</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Crystal structure ; Devices ; Electrochemical properties ; Exact sciences and technology ; Metal 1,2-dithiolenes ; Optical properties ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Optical properties of bulk materials and thin films ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Solid state sciences, 2008-12, Vol.10 (12), p.1729-1733</ispartof><rights>2008 Elsevier Masson SAS</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c469t-c3d4c459f0f1cf6b488a5331cc9a8a93d55959f872dba931906f3c4c443925f93</citedby><cites>FETCH-LOGICAL-c469t-c3d4c459f0f1cf6b488a5331cc9a8a93d55959f872dba931906f3c4c443925f93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.solidstatesciences.2008.03.012$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>310,311,315,781,785,790,791,3551,23935,23936,25145,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20991987$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Anyfantis, George C.</creatorcontrib><creatorcontrib>Papavassiliou, George C.</creatorcontrib><creatorcontrib>Assimomytis, Nikos</creatorcontrib><creatorcontrib>Terzis, Aris</creatorcontrib><creatorcontrib>Psycharis, Vassilis</creatorcontrib><creatorcontrib>Raptopoulou, Catherine P.</creatorcontrib><creatorcontrib>Kyritsis, Panayotis</creatorcontrib><creatorcontrib>Thoma, Vladimiros</creatorcontrib><creatorcontrib>Koutselas, Ioannis B.</creatorcontrib><title>Some unsymmetrical nickel 1,2-dithiolene complexes as candidate materials for optics and electronics</title><title>Solid state sciences</title><description>The unsymmetrical complexes Ni(tmedt)(dddt), Ni(dpedt)(dddt), Ni(tmedt)(dmit), and Ni(dpedt)(dmio) (where tmedt is trimethylene-ethylenedithiolate, dddt is 5,6-dihydro-1,4-dithin-2,3-dithiolate, dmit is 1,3-dithiol-2-thione-4,5-dithiolate, dpedt is diphenyl-ethylenedithiolate, and dmio is 1,3-dithiol-2-one-4,5-dithiolate) were prepared and their structural and physical properties investigated. The results were compared with those obtained from similar unsymmetrical and the corresponding symmetrical complexes. The new complexes were found to be stable in air and exhibit the necessary structural and physical properties in order to be candidate materials for optical and electronic devices.
Unsymmetrical nickel 1,2-dithiolene complexes, which exhibit LUMO and HOMO levels around the Fermi energy level of Au, are suitable materials for optical and electronic devices.
[Display omitted]</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Crystal structure</subject><subject>Devices</subject><subject>Electrochemical properties</subject><subject>Exact sciences and technology</subject><subject>Metal 1,2-dithiolenes</subject><subject>Optical properties</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Optical properties of bulk materials and thin films</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>1293-2558</issn><issn>1873-3085</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqNkU9vFCEYh4mxiXXrd-Ci8eCMMAyzcNM0Vds08VA9E_ryElmZYeWdbey3l2Y3Xrx44U94-P3CA2NvpeilkNP7XU8lp0CrX5Eg4QJI_SCE6YXqhRyesXNptqpTwujnbT1Y1Q1amxfsJdFOCDFN2_GchbsyIz8s9DjPuNYEPvMlwU_MXL4bupDWH6lkXJBDmfcZfyNxTxz8ElJo1XxuQ00-E4-l8rJfEzRiCRwzwlpLC6MLdhYbga9O84Z9_3T17fJLd_v18_Xlx9sOxsmuHagwwqhtFFFCnO5HY7xWSgJYb7xVQWvbTs12CPdtK62YooJ2ZVR20NGqDXtzzN3X8uuAtLo5EWDOfsFyIKf0pEejpwZ-OIJQC1HF6PY1zb4-Oinck163c__qdU96nVCu6W0Rr09dnpq0WP0Cif7mDMJaadsHbNjNkcP28IeE1Z3iQqpNkAsl_X_pH2OlnrI</recordid><startdate>20081201</startdate><enddate>20081201</enddate><creator>Anyfantis, George C.</creator><creator>Papavassiliou, George C.</creator><creator>Assimomytis, Nikos</creator><creator>Terzis, Aris</creator><creator>Psycharis, Vassilis</creator><creator>Raptopoulou, Catherine P.</creator><creator>Kyritsis, Panayotis</creator><creator>Thoma, Vladimiros</creator><creator>Koutselas, Ioannis B.</creator><general>Elsevier Masson SAS</general><general>Elsevier Masson</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20081201</creationdate><title>Some unsymmetrical nickel 1,2-dithiolene complexes as candidate materials for optics and electronics</title><author>Anyfantis, George C. ; 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crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Anyfantis, George C.</creatorcontrib><creatorcontrib>Papavassiliou, George C.</creatorcontrib><creatorcontrib>Assimomytis, Nikos</creatorcontrib><creatorcontrib>Terzis, Aris</creatorcontrib><creatorcontrib>Psycharis, Vassilis</creatorcontrib><creatorcontrib>Raptopoulou, Catherine P.</creatorcontrib><creatorcontrib>Kyritsis, Panayotis</creatorcontrib><creatorcontrib>Thoma, Vladimiros</creatorcontrib><creatorcontrib>Koutselas, Ioannis B.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Anyfantis, George C.</au><au>Papavassiliou, George C.</au><au>Assimomytis, Nikos</au><au>Terzis, Aris</au><au>Psycharis, Vassilis</au><au>Raptopoulou, Catherine P.</au><au>Kyritsis, Panayotis</au><au>Thoma, Vladimiros</au><au>Koutselas, Ioannis B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Some unsymmetrical nickel 1,2-dithiolene complexes as candidate materials for optics and electronics</atitle><jtitle>Solid state sciences</jtitle><date>2008-12-01</date><risdate>2008</risdate><volume>10</volume><issue>12</issue><spage>1729</spage><epage>1733</epage><pages>1729-1733</pages><issn>1293-2558</issn><eissn>1873-3085</eissn><abstract>The unsymmetrical complexes Ni(tmedt)(dddt), Ni(dpedt)(dddt), Ni(tmedt)(dmit), and Ni(dpedt)(dmio) (where tmedt is trimethylene-ethylenedithiolate, dddt is 5,6-dihydro-1,4-dithin-2,3-dithiolate, dmit is 1,3-dithiol-2-thione-4,5-dithiolate, dpedt is diphenyl-ethylenedithiolate, and dmio is 1,3-dithiol-2-one-4,5-dithiolate) were prepared and their structural and physical properties investigated. The results were compared with those obtained from similar unsymmetrical and the corresponding symmetrical complexes. The new complexes were found to be stable in air and exhibit the necessary structural and physical properties in order to be candidate materials for optical and electronic devices.
Unsymmetrical nickel 1,2-dithiolene complexes, which exhibit LUMO and HOMO levels around the Fermi energy level of Au, are suitable materials for optical and electronic devices.
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| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Crystal structure Devices Electrochemical properties Exact sciences and technology Metal 1,2-dithiolenes Optical properties Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Some unsymmetrical nickel 1,2-dithiolene complexes as candidate materials for optics and electronics |
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