Calculation of phase diagrams of heterophase two- and three-component liquid mixtures ‘α-pinene–water’ and ‘α-pinene–water–ethanol’
Phase behaviors of two- and three-component mixtures ‘α-pinene–water’ and ‘α-pinene–ethanol–water’ were studied over a wide range of their composition, temperature, and pressure. Conditions were found that provide heteroazeotropic states of binary mixture ‘α-pinene–water’ and ternary mixture ‘α-pine...
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| Veröffentlicht in: | Chemical engineering science 2008-12, Vol.63 (24), p.5854-5859 |
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| container_title | Chemical engineering science |
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| creator | Yermakova, A. Chibiryaev, A.M. Kozhevnikov, I.V. Anikeev, V.I. |
| description | Phase behaviors of two- and three-component mixtures ‘α-pinene–water’ and ‘α-pinene–ethanol–water’ were studied over a wide range of their composition, temperature, and pressure. Conditions were found that provide heteroazeotropic states of binary mixture ‘α-pinene–water’ and ternary mixture ‘α-pinene–ethanol–water’ depending on the ratio of ‘water/(α-pinene+ethanol)’ fractions at the ‘α-pinene+ethanol’ ratio of 1:1. Critical curves were calculated to demonstrate an anomalous dependence of these curves on the mixture composition, with the temperature minimum points typical of the mixtures that form heteroazeotropes. |
| doi_str_mv | 10.1016/j.ces.2008.08.020 |
| format | Article |
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Critical curves were calculated to demonstrate an anomalous dependence of these curves on the mixture composition, with the temperature minimum points typical of the mixtures that form heteroazeotropes.</description><subject>Critical curve</subject><subject>Heteroazeotropic state</subject><subject>Phase behavior</subject><subject>Supercritical conditions</subject><subject>Thermodynamic</subject><subject>Two- and three-component mixtures</subject><subject>‘α-Pinene–water’ and ‘α-pinene–ethanol–water’</subject><issn>0009-2509</issn><issn>1873-4405</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kM-O0zAQxi3ESpQuD8AtF7iljO06ccUJVfxZaSUu7NlynDF1lcRZ22Hh1nfoBR6DF9mH6JPg0BWnFdJIo5n5zTeaj5CXFFYUaPVmvzIYVwxAruZg8IQsqKx5uV6DeEoWALApmYDNM_I8xn0u65rCghy3ujNTp5PzQ-FtMe50xKJ1-mvQfZw7O0wY_Lmf7nxZ6KEt0i4glsb3ox9wSEXnbifXFr37nqaAsTgdft7_LkeXh3g6HO901jgdfv3dfXx2xLTTg-8ydUkurO4ivnjIS3Lz4f2X7afy-vPHq-2769JwIVOpubTM0gataIDZVorKNo2lFW3XEiqgmgHPjgCvjeYb0_C6wWYjmNS1BI58SV6fdcfgbyeMSfUuGuw6PaCfouKiEozSOoP0DJrgYwxo1Rhcr8MPRUHN9qu9yvar2X41Rz68JK8exHU0urNBD8bFf4sMpKiB88y9PXOYP_3mMKhoHA4GWxfQJNV6958rfwDsgqVL</recordid><startdate>200812</startdate><enddate>200812</enddate><creator>Yermakova, A.</creator><creator>Chibiryaev, A.M.</creator><creator>Kozhevnikov, I.V.</creator><creator>Anikeev, V.I.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>L7M</scope></search><sort><creationdate>200812</creationdate><title>Calculation of phase diagrams of heterophase two- and three-component liquid mixtures ‘α-pinene–water’ and ‘α-pinene–water–ethanol’</title><author>Yermakova, A. ; Chibiryaev, A.M. ; Kozhevnikov, I.V. ; Anikeev, V.I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-a38f2f1bef5b02fd856fbbf161d480601a203200037ca39cb37beb9528a7803e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Critical curve</topic><topic>Heteroazeotropic state</topic><topic>Phase behavior</topic><topic>Supercritical conditions</topic><topic>Thermodynamic</topic><topic>Two- and three-component mixtures</topic><topic>‘α-Pinene–water’ and ‘α-pinene–ethanol–water’</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yermakova, A.</creatorcontrib><creatorcontrib>Chibiryaev, A.M.</creatorcontrib><creatorcontrib>Kozhevnikov, I.V.</creatorcontrib><creatorcontrib>Anikeev, V.I.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical engineering science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yermakova, A.</au><au>Chibiryaev, A.M.</au><au>Kozhevnikov, I.V.</au><au>Anikeev, V.I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Calculation of phase diagrams of heterophase two- and three-component liquid mixtures ‘α-pinene–water’ and ‘α-pinene–water–ethanol’</atitle><jtitle>Chemical engineering science</jtitle><date>2008-12</date><risdate>2008</risdate><volume>63</volume><issue>24</issue><spage>5854</spage><epage>5859</epage><pages>5854-5859</pages><issn>0009-2509</issn><eissn>1873-4405</eissn><coden>CESCAC</coden><abstract>Phase behaviors of two- and three-component mixtures ‘α-pinene–water’ and ‘α-pinene–ethanol–water’ were studied over a wide range of their composition, temperature, and pressure. Conditions were found that provide heteroazeotropic states of binary mixture ‘α-pinene–water’ and ternary mixture ‘α-pinene–ethanol–water’ depending on the ratio of ‘water/(α-pinene+ethanol)’ fractions at the ‘α-pinene+ethanol’ ratio of 1:1. Critical curves were calculated to demonstrate an anomalous dependence of these curves on the mixture composition, with the temperature minimum points typical of the mixtures that form heteroazeotropes.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.ces.2008.08.020</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 0009-2509 |
| ispartof | Chemical engineering science, 2008-12, Vol.63 (24), p.5854-5859 |
| issn | 0009-2509 1873-4405 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Critical curve Heteroazeotropic state Phase behavior Supercritical conditions Thermodynamic Two- and three-component mixtures ‘α-Pinene–water’ and ‘α-pinene–ethanol–water’ |
| title | Calculation of phase diagrams of heterophase two- and three-component liquid mixtures ‘α-pinene–water’ and ‘α-pinene–water–ethanol’ |
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