Wettability of carbon surfaces by pure molten alkali chlorides and their penetration into a porous graphite substrate
The wettability of graphite and glassy carbon surfaces by pure molten alkali chlorides (NaCl, KCl, RbCl, CsCl) was measured by the sessile drop method. The contact angle was found to decrease with increase of the cation radius of the chloride. Using our measured and available literature data, a new,...
Gespeichert in:
| Veröffentlicht in: | Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2008-11, Vol.495 (1), p.192-196 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 196 |
|---|---|
| container_issue | 1 |
| container_start_page | 192 |
| container_title | Materials science & engineering. A, Structural materials : properties, microstructure and processing |
| container_volume | 495 |
| creator | Baumli, P. Kaptay, G. |
| description | The wettability of graphite and glassy carbon surfaces by pure molten alkali chlorides (NaCl, KCl, RbCl, CsCl) was measured by the sessile drop method. The contact angle was found to decrease with increase of the cation radius of the chloride. Using our measured and available literature data, a new, semi-empirical model is established to estimate the adhesion energy between the 20 alkali halide molten salts and graphite (or glassy carbon). The adhesion energy is found to increase with square of the radius of the cation, and the inverse of the radius of the anion of the salt. The minimum possible value for the surface energy of graphite (and glassy carbon) was found as 150
±
30
mJ/m
2. The critical contact angle of spontaneous penetration (infiltration) of the molten chlorides into a porous graphite substrate was found experimentally below 90°, in the interval between 31° and 58°. This is explained by the inner structure of the porous graphite. |
| doi_str_mv | 10.1016/j.msea.2007.11.093 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_35619794</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0921509308001652</els_id><sourcerecordid>35619794</sourcerecordid><originalsourceid>FETCH-LOGICAL-c361t-d4ca815a5080ff9b4623ed95d664bc86c03954be9e391d0d69d401fdb474ead13</originalsourceid><addsrcrecordid>eNp9kMFu3CAURVHVSpmm_YGs2LQ7O2AwHqRuoqhpI0XKJlGX6BmeO0wZ4wCuNH9fRhN1mRXS49z74BByxVnLGVfX-_aQEdqOsaHlvGVavCMbvh1EI7VQ78mG6Y43fZ1fkI857xljXLJ-Q9ZfWAqMPvhypHGiFtIYZ5rXNIHFTMcjXdaE9BBDwZlC-APBU7sLMXlX72F2tOzQJ7rgjCVB8TXu5xIp0CWmuGb6O8Gy8wVr65hPCH4iHyYIGT-_npfk-e770-3P5uHxx_3tzUNjheKlcdLClvfQsy2bJj1K1Ql0undKydFulWVC93JEjUJzx5zSTjI-uVEOEsFxcUm-nnuXFF9WzMUcfLYYAsxYX2ZEr7getKxgdwZtijknnMyS_AHS0XBmTobN3pwMm5Nhw7mpJmvoy2s7ZAthSjBbn_8nOzboqn2o3Lczh_Wrfz0mk63H2aLzCW0xLvq31vwDIg-UVA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>35619794</pqid></control><display><type>article</type><title>Wettability of carbon surfaces by pure molten alkali chlorides and their penetration into a porous graphite substrate</title><source>Access via ScienceDirect (Elsevier)</source><creator>Baumli, P. ; Kaptay, G.</creator><creatorcontrib>Baumli, P. ; Kaptay, G.</creatorcontrib><description>The wettability of graphite and glassy carbon surfaces by pure molten alkali chlorides (NaCl, KCl, RbCl, CsCl) was measured by the sessile drop method. The contact angle was found to decrease with increase of the cation radius of the chloride. Using our measured and available literature data, a new, semi-empirical model is established to estimate the adhesion energy between the 20 alkali halide molten salts and graphite (or glassy carbon). The adhesion energy is found to increase with square of the radius of the cation, and the inverse of the radius of the anion of the salt. The minimum possible value for the surface energy of graphite (and glassy carbon) was found as 150
±
30
mJ/m
2. The critical contact angle of spontaneous penetration (infiltration) of the molten chlorides into a porous graphite substrate was found experimentally below 90°, in the interval between 31° and 58°. This is explained by the inner structure of the porous graphite.</description><identifier>ISSN: 0921-5093</identifier><identifier>EISSN: 1873-4936</identifier><identifier>DOI: 10.1016/j.msea.2007.11.093</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Adhesion energy ; Alkali halide ; Condensed matter: structure, mechanical and thermal properties ; Contact angle ; Exact sciences and technology ; Glassy carbon ; Graphite ; Infiltration ; Penetration ; Physics ; Solid-fluid interfaces ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) ; Wettability ; Wetting</subject><ispartof>Materials science & engineering. A, Structural materials : properties, microstructure and processing, 2008-11, Vol.495 (1), p.192-196</ispartof><rights>2008 Elsevier B.V.</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-d4ca815a5080ff9b4623ed95d664bc86c03954be9e391d0d69d401fdb474ead13</citedby><cites>FETCH-LOGICAL-c361t-d4ca815a5080ff9b4623ed95d664bc86c03954be9e391d0d69d401fdb474ead13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.msea.2007.11.093$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>310,311,315,782,786,791,792,3554,23939,23940,25149,27933,27934,46004</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20790927$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Baumli, P.</creatorcontrib><creatorcontrib>Kaptay, G.</creatorcontrib><title>Wettability of carbon surfaces by pure molten alkali chlorides and their penetration into a porous graphite substrate</title><title>Materials science & engineering. A, Structural materials : properties, microstructure and processing</title><description>The wettability of graphite and glassy carbon surfaces by pure molten alkali chlorides (NaCl, KCl, RbCl, CsCl) was measured by the sessile drop method. The contact angle was found to decrease with increase of the cation radius of the chloride. Using our measured and available literature data, a new, semi-empirical model is established to estimate the adhesion energy between the 20 alkali halide molten salts and graphite (or glassy carbon). The adhesion energy is found to increase with square of the radius of the cation, and the inverse of the radius of the anion of the salt. The minimum possible value for the surface energy of graphite (and glassy carbon) was found as 150
±
30
mJ/m
2. The critical contact angle of spontaneous penetration (infiltration) of the molten chlorides into a porous graphite substrate was found experimentally below 90°, in the interval between 31° and 58°. This is explained by the inner structure of the porous graphite.</description><subject>Adhesion energy</subject><subject>Alkali halide</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Contact angle</subject><subject>Exact sciences and technology</subject><subject>Glassy carbon</subject><subject>Graphite</subject><subject>Infiltration</subject><subject>Penetration</subject><subject>Physics</subject><subject>Solid-fluid interfaces</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>Wettability</subject><subject>Wetting</subject><issn>0921-5093</issn><issn>1873-4936</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kMFu3CAURVHVSpmm_YGs2LQ7O2AwHqRuoqhpI0XKJlGX6BmeO0wZ4wCuNH9fRhN1mRXS49z74BByxVnLGVfX-_aQEdqOsaHlvGVavCMbvh1EI7VQ78mG6Y43fZ1fkI857xljXLJ-Q9ZfWAqMPvhypHGiFtIYZ5rXNIHFTMcjXdaE9BBDwZlC-APBU7sLMXlX72F2tOzQJ7rgjCVB8TXu5xIp0CWmuGb6O8Gy8wVr65hPCH4iHyYIGT-_npfk-e770-3P5uHxx_3tzUNjheKlcdLClvfQsy2bJj1K1Ql0undKydFulWVC93JEjUJzx5zSTjI-uVEOEsFxcUm-nnuXFF9WzMUcfLYYAsxYX2ZEr7getKxgdwZtijknnMyS_AHS0XBmTobN3pwMm5Nhw7mpJmvoy2s7ZAthSjBbn_8nOzboqn2o3Lczh_Wrfz0mk63H2aLzCW0xLvq31vwDIg-UVA</recordid><startdate>20081115</startdate><enddate>20081115</enddate><creator>Baumli, P.</creator><creator>Kaptay, G.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20081115</creationdate><title>Wettability of carbon surfaces by pure molten alkali chlorides and their penetration into a porous graphite substrate</title><author>Baumli, P. ; Kaptay, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-d4ca815a5080ff9b4623ed95d664bc86c03954be9e391d0d69d401fdb474ead13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Adhesion energy</topic><topic>Alkali halide</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Contact angle</topic><topic>Exact sciences and technology</topic><topic>Glassy carbon</topic><topic>Graphite</topic><topic>Infiltration</topic><topic>Penetration</topic><topic>Physics</topic><topic>Solid-fluid interfaces</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><topic>Wettability</topic><topic>Wetting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baumli, P.</creatorcontrib><creatorcontrib>Kaptay, G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials science & engineering. A, Structural materials : properties, microstructure and processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baumli, P.</au><au>Kaptay, G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Wettability of carbon surfaces by pure molten alkali chlorides and their penetration into a porous graphite substrate</atitle><jtitle>Materials science & engineering. A, Structural materials : properties, microstructure and processing</jtitle><date>2008-11-15</date><risdate>2008</risdate><volume>495</volume><issue>1</issue><spage>192</spage><epage>196</epage><pages>192-196</pages><issn>0921-5093</issn><eissn>1873-4936</eissn><abstract>The wettability of graphite and glassy carbon surfaces by pure molten alkali chlorides (NaCl, KCl, RbCl, CsCl) was measured by the sessile drop method. The contact angle was found to decrease with increase of the cation radius of the chloride. Using our measured and available literature data, a new, semi-empirical model is established to estimate the adhesion energy between the 20 alkali halide molten salts and graphite (or glassy carbon). The adhesion energy is found to increase with square of the radius of the cation, and the inverse of the radius of the anion of the salt. The minimum possible value for the surface energy of graphite (and glassy carbon) was found as 150
±
30
mJ/m
2. The critical contact angle of spontaneous penetration (infiltration) of the molten chlorides into a porous graphite substrate was found experimentally below 90°, in the interval between 31° and 58°. This is explained by the inner structure of the porous graphite.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.msea.2007.11.093</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0921-5093 |
| ispartof | Materials science & engineering. A, Structural materials : properties, microstructure and processing, 2008-11, Vol.495 (1), p.192-196 |
| issn | 0921-5093 1873-4936 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_35619794 |
| source | Access via ScienceDirect (Elsevier) |
| subjects | Adhesion energy Alkali halide Condensed matter: structure, mechanical and thermal properties Contact angle Exact sciences and technology Glassy carbon Graphite Infiltration Penetration Physics Solid-fluid interfaces Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) Wettability Wetting |
| title | Wettability of carbon surfaces by pure molten alkali chlorides and their penetration into a porous graphite substrate |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-03T03%3A00%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Wettability%20of%20carbon%20surfaces%20by%20pure%20molten%20alkali%20chlorides%20and%20their%20penetration%20into%20a%20porous%20graphite%20substrate&rft.jtitle=Materials%20science%20&%20engineering.%20A,%20Structural%20materials%20:%20properties,%20microstructure%20and%20processing&rft.au=Baumli,%20P.&rft.date=2008-11-15&rft.volume=495&rft.issue=1&rft.spage=192&rft.epage=196&rft.pages=192-196&rft.issn=0921-5093&rft.eissn=1873-4936&rft_id=info:doi/10.1016/j.msea.2007.11.093&rft_dat=%3Cproquest_cross%3E35619794%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=35619794&rft_id=info:pmid/&rft_els_id=S0921509308001652&rfr_iscdi=true |