Influence of growth temperature and V/III ratio on the optical characteristics of narrow band gap (0.77 eV) InN grown on GaN/sapphire using pulsed MOVPE

In this study, we report on the pulsed metalorganic vapor phase epitaxy (MOVPE) of InN as well as the optical and electronic properties of the films as a function of V/III ratio and growth temperatures. The growth of InN films was conducted utilizing a vertical reactor with TMIn and NH 3 as the In-...

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Veröffentlicht in:Journal of crystal growth 2008-11, Vol.310 (23), p.4947-4953
Hauptverfasser: Jamil, Muhammad, Zhao, Hongping, Higgins, John B., Tansu, Nelson
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container_end_page 4953
container_issue 23
container_start_page 4947
container_title Journal of crystal growth
container_volume 310
creator Jamil, Muhammad
Zhao, Hongping
Higgins, John B.
Tansu, Nelson
description In this study, we report on the pulsed metalorganic vapor phase epitaxy (MOVPE) of InN as well as the optical and electronic properties of the films as a function of V/III ratio and growth temperatures. The growth of InN films was conducted utilizing a vertical reactor with TMIn and NH 3 as the In- and N-precursors, respectively. Metallic droplet-free InN films were achieved on GaN/sapphire template in a pulsed MOVPE mode with low V/III ratio condition. In the pulsed growth mode, NH 3 was constantly flowing while the TMIn was sent into the reactor chamber for a 36-s pulse and then it bypassed the reactor chamber for an 18-s pulse for a total cycle time of 54 s. At a growth pressure of 200 Torr, the effects of growth temperature (510–575 °C) and V/III ratio (12,460–17,100) on the photoluminescence (PL) transitions were investigated. Morphological evolution as well as the electrical quality of the overgrown films have also been studied for the given growth conditions.
doi_str_mv 10.1016/j.jcrysgro.2008.07.122
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subjects A1. Photoluminescence
A3. MOCVD
B1. Nitrides
B2. InN
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of crystal growth
physics of crystal growth
Methods of deposition of films and coatings
film growth and epitaxy
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of bulk materials and thin films
Photoluminescence
Physics
Theory and models of crystal growth
physics of crystal growth, crystal morphology and orientation
Vapor phase epitaxy
growth from vapor phase
title Influence of growth temperature and V/III ratio on the optical characteristics of narrow band gap (0.77 eV) InN grown on GaN/sapphire using pulsed MOVPE
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