Polystyrene composites containing crosslinked polystyrene-multiwalled carbon nanotube balls
Crosslinked polystyrene-multiwalled carbon nanotube (PS-MWCNT) balls, which act as conductive microfillers, were prepared by the in situ suspension polymerization of styrene with MWCNTs and divinyl benzene (DVB) as a crosslinking agent. The diameters of the synthesized crosslinked PS-MWCNT balls ran...
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Veröffentlicht in: | Journal of applied polymer science 2008-12, Vol.110 (6), p.3737-3744 |
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creator | Kwon, Soon-Min Kim, Hun-Sik Kim, Don-Young Yun, Young Soo Jin, Hyoung-Joon |
description | Crosslinked polystyrene-multiwalled carbon nanotube (PS-MWCNT) balls, which act as conductive microfillers, were prepared by the in situ suspension polymerization of styrene with MWCNTs and divinyl benzene (DVB) as a crosslinking agent. The diameters of the synthesized crosslinked PS-MWCNT balls ranged from 10 to 100 μm and their electrical conductivity was about 7.7 x 10⁻³ S/cm. The morphology of the crosslinked PS-MWCNT balls was observed by scanning electron microscopy and transmission electron microscopy. The change in the chemical structure of the MWCNTs was confirmed by Raman spectroscopy and Fourier transform infrared spectroscopy. The mechanical and electrical properties of the PS/crosslinked PS-MWCNT ball composites were investigated. It was found that the tensile strength, ultimate strain, Young's modulus, and impact strength of the PS matrix were enhanced by the incorporation of the crosslinked PS-MWCNT balls. In addition, the mechanical properties of the PS/crosslinked PS-MWCNT ball composites were better than those of the PS/pristine MWCNT composites. |
doi_str_mv | 10.1002/app.29002 |
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The diameters of the synthesized crosslinked PS-MWCNT balls ranged from 10 to 100 μm and their electrical conductivity was about 7.7 x 10⁻³ S/cm. The morphology of the crosslinked PS-MWCNT balls was observed by scanning electron microscopy and transmission electron microscopy. The change in the chemical structure of the MWCNTs was confirmed by Raman spectroscopy and Fourier transform infrared spectroscopy. The mechanical and electrical properties of the PS/crosslinked PS-MWCNT ball composites were investigated. It was found that the tensile strength, ultimate strain, Young's modulus, and impact strength of the PS matrix were enhanced by the incorporation of the crosslinked PS-MWCNT balls. In addition, the mechanical properties of the PS/crosslinked PS-MWCNT ball composites were better than those of the PS/pristine MWCNT composites.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.29002</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Composites ; conductive microfiller ; Exact sciences and technology ; Forms of application and semi-finished materials ; multiwalled carbon nanotubes ; Polymer industry, paints, wood ; polystyrene ; solution casting ; suspension polymerization ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 2008-12, Vol.110 (6), p.3737-3744</ispartof><rights>Copyright © 2008 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3922-5454397fa393a742559848d6d4a5d340f812875e4c74f40fa2cc95ce93bdda13</citedby><cites>FETCH-LOGICAL-c3922-5454397fa393a742559848d6d4a5d340f812875e4c74f40fa2cc95ce93bdda13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.29002$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.29002$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27907,27908,45557,45558</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20869504$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kwon, Soon-Min</creatorcontrib><creatorcontrib>Kim, Hun-Sik</creatorcontrib><creatorcontrib>Kim, Don-Young</creatorcontrib><creatorcontrib>Yun, Young Soo</creatorcontrib><creatorcontrib>Jin, Hyoung-Joon</creatorcontrib><title>Polystyrene composites containing crosslinked polystyrene-multiwalled carbon nanotube balls</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>Crosslinked polystyrene-multiwalled carbon nanotube (PS-MWCNT) balls, which act as conductive microfillers, were prepared by the in situ suspension polymerization of styrene with MWCNTs and divinyl benzene (DVB) as a crosslinking agent. The diameters of the synthesized crosslinked PS-MWCNT balls ranged from 10 to 100 μm and their electrical conductivity was about 7.7 x 10⁻³ S/cm. The morphology of the crosslinked PS-MWCNT balls was observed by scanning electron microscopy and transmission electron microscopy. The change in the chemical structure of the MWCNTs was confirmed by Raman spectroscopy and Fourier transform infrared spectroscopy. The mechanical and electrical properties of the PS/crosslinked PS-MWCNT ball composites were investigated. It was found that the tensile strength, ultimate strain, Young's modulus, and impact strength of the PS matrix were enhanced by the incorporation of the crosslinked PS-MWCNT balls. In addition, the mechanical properties of the PS/crosslinked PS-MWCNT ball composites were better than those of the PS/pristine MWCNT composites.</description><subject>Applied sciences</subject><subject>Composites</subject><subject>conductive microfiller</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>multiwalled carbon nanotubes</subject><subject>Polymer industry, paints, wood</subject><subject>polystyrene</subject><subject>solution casting</subject><subject>suspension polymerization</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp1kEtP3DAUhS1UpE4pi_6CZtNKLAJ-JvaSIkpBCKY8RKUurDuOg1w8drAzovPvMYTCqitfH33n6N6D0CeCdwnGdA-GYZeqMm2gGcGqrXlD5Ts0KwqppVLiPfqQ8x-MCRG4maHf8-jXeVwnG2xl4nKI2Y02lzGM4IILt5VJMWfvwp3tquGNrpcrP7oH8L7oBtIihipAiONqYatFkfNHtNmDz3b75d1CV98Prw5-1KfnR8cH-6e1YYrSWnDBmWp7YIpBy6kQSnLZNR0H0TGOe0mobIXlpuV9-QI1RgljFVt0HRC2hb5OsUOK9yubR7102VjvIdi4ypoJLkWpooA7E_h8UbK9HpJbQlprgvVTe7q0p5_bK-yXl1DIBnyfIBiXXw0Uy0YJzAu3N3EPztv1_wP1_nz-L7meHC6P9u-rA9KdblrWCn1zdqQvfl2efCMXPzUu_OeJ7yFquE1li-tLignDpBwmBWGPcRuYVw</recordid><startdate>20081215</startdate><enddate>20081215</enddate><creator>Kwon, Soon-Min</creator><creator>Kim, Hun-Sik</creator><creator>Kim, Don-Young</creator><creator>Yun, Young Soo</creator><creator>Jin, Hyoung-Joon</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20081215</creationdate><title>Polystyrene composites containing crosslinked polystyrene-multiwalled carbon nanotube balls</title><author>Kwon, Soon-Min ; Kim, Hun-Sik ; Kim, Don-Young ; Yun, Young Soo ; Jin, Hyoung-Joon</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3922-5454397fa393a742559848d6d4a5d340f812875e4c74f40fa2cc95ce93bdda13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>conductive microfiller</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>multiwalled carbon nanotubes</topic><topic>Polymer industry, paints, wood</topic><topic>polystyrene</topic><topic>solution casting</topic><topic>suspension polymerization</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kwon, Soon-Min</creatorcontrib><creatorcontrib>Kim, Hun-Sik</creatorcontrib><creatorcontrib>Kim, Don-Young</creatorcontrib><creatorcontrib>Yun, Young Soo</creatorcontrib><creatorcontrib>Jin, Hyoung-Joon</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kwon, Soon-Min</au><au>Kim, Hun-Sik</au><au>Kim, Don-Young</au><au>Yun, Young Soo</au><au>Jin, Hyoung-Joon</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polystyrene composites containing crosslinked polystyrene-multiwalled carbon nanotube balls</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2008-12-15</date><risdate>2008</risdate><volume>110</volume><issue>6</issue><spage>3737</spage><epage>3744</epage><pages>3737-3744</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Crosslinked polystyrene-multiwalled carbon nanotube (PS-MWCNT) balls, which act as conductive microfillers, were prepared by the in situ suspension polymerization of styrene with MWCNTs and divinyl benzene (DVB) as a crosslinking agent. The diameters of the synthesized crosslinked PS-MWCNT balls ranged from 10 to 100 μm and their electrical conductivity was about 7.7 x 10⁻³ S/cm. The morphology of the crosslinked PS-MWCNT balls was observed by scanning electron microscopy and transmission electron microscopy. The change in the chemical structure of the MWCNTs was confirmed by Raman spectroscopy and Fourier transform infrared spectroscopy. The mechanical and electrical properties of the PS/crosslinked PS-MWCNT ball composites were investigated. It was found that the tensile strength, ultimate strain, Young's modulus, and impact strength of the PS matrix were enhanced by the incorporation of the crosslinked PS-MWCNT balls. In addition, the mechanical properties of the PS/crosslinked PS-MWCNT ball composites were better than those of the PS/pristine MWCNT composites.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.29002</doi><tpages>8</tpages></addata></record> |
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subjects | Applied sciences Composites conductive microfiller Exact sciences and technology Forms of application and semi-finished materials multiwalled carbon nanotubes Polymer industry, paints, wood polystyrene solution casting suspension polymerization Technology of polymers |
title | Polystyrene composites containing crosslinked polystyrene-multiwalled carbon nanotube balls |
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